{"id":"W2735010495","doi":"10.1002/asia.201700794","title":"Photoinduced Electron Transfer‐based Halogen‐free Photosensitizers: Covalent <i>meso</i>‐Aryl (Phenyl, Naphthyl, Anthryl, and Pyrenyl) as Electron Donors to Effectively Induce the Formation of the Excited Triplet State and Singlet Oxygen for BODIPY Compounds","year":2017,"lang":"en","type":"article","venue":"Chemistry - An Asian Journal","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":85,"is_retracted":false,"has_abstract":true,"ca_institutions":"Royal Ontario Museum","funders":"","keywords":"Photochemistry; BODIPY; Chemistry; Singlet oxygen; Quantum yield; Flash photolysis; Photoinduced electron transfer; Singlet state; Triplet state; Aryl; Electron transfer; Fluorescence; Excited state; Oxygen; Reaction rate constant; Molecule; Kinetics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009923625,0.0002525168,0.0001020728,0.00007264178,0.00007449411,0.0001196475,0.0001434469,0.0002043404,0.0007514904],"category_scores_gemma":[0.00009509047,0.00009797628,0.0001258714,0.00006759302,0.0001415051,0.000191415,0.000155475,0.0002817922,0.0001352242],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001810538,"about_ca_system_score_gemma":0.0001021506,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002851993,"about_ca_topic_score_gemma":0.0005549005,"domain_scores_codex":[0.9999486,0.000007080678,0.000003390575,0.00001249405,0.00001526115,0.00001316002],"domain_scores_gemma":[0.9999458,0.00001115787,0.00001844035,0.000007832822,0.000007927094,0.000008826943],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001177734,0.000006465492,0.00002269553,0.00001731758,0.000001556709,0.000009245082,0.000004549333,0.00004147015,0.9994304,0.00004538293,0.00001316824,0.0003959784],"study_design_scores_gemma":[0.00000340309,0.00006053832,0.0003525506,0.000001260802,0.000003657281,0.00002249382,0.000002793021,0.0003958538,0.9987615,0.000007118346,0.0003872186,0.000001423548],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.994938,0.000552647,0.003515627,0.00003622508,0.00001468323,0.00001653595,0.00006176707,0.00004629636,0.000818172],"genre_scores_gemma":[0.9965196,0.0002802711,0.002079022,0.00002245135,0.000004148629,0.00001665894,0.00006607983,0.000009797004,0.001002084],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007514904,"threshold_uncertainty_score":0.002514005,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01606726015200197,"score_gpt":0.2605646789651991,"score_spread":0.2444974188131971,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}