{"id":"W2735010495","doi":"10.1002/asia.201700794","title":"Photoinduced Electron Transfer‐based Halogen‐free Photosensitizers: Covalent <i>meso</i>‐Aryl (Phenyl, Naphthyl, Anthryl, and Pyrenyl) as Electron Donors to Effectively Induce the Formation of the Excited Triplet State and Singlet Oxygen for BODIPY Compounds","year":2017,"lang":"en","type":"article","venue":"Chemistry - An Asian Journal","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":85,"is_retracted":false,"has_abstract":true,"ca_institutions":"Royal Ontario Museum","funders":"","keywords":"Photochemistry; BODIPY; Chemistry; Singlet oxygen; Quantum yield; Flash photolysis; Photoinduced electron transfer; Singlet state; Triplet state; Aryl; Electron transfer; Fluorescence; Excited state; Oxygen; Reaction rate constant; Molecule; Kinetics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00115972,0.0003542725,0.0004557919,0.00005298447,0.001296362,0.0008011207,0.0008482086,0.0001400054,0.00003184417],"category_scores_gemma":[0.0002110747,0.0002380234,0.000127856,0.00008223832,0.0004359183,0.0005875216,0.00009062703,0.0002732805,0.000001856953],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001185054,"about_ca_system_score_gemma":0.0002473826,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004126341,"about_ca_topic_score_gemma":0.00002847314,"domain_scores_codex":[0.9978642,0.0001562908,0.0005714507,0.0004075812,0.0003993679,0.0006011363],"domain_scores_gemma":[0.9982846,0.00006998704,0.0004785231,0.0006907887,0.0002142161,0.0002618954],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001187467,0.00009732554,0.0001759584,0.0001815022,0.00002614165,0.000007174724,0.001210666,0.000003479022,0.9964803,0.000005364469,0.0003126225,0.0003119795],"study_design_scores_gemma":[0.002957624,0.0005142404,0.003015579,0.0002251795,0.00007855735,0.0003093885,0.0003511183,0.0001609276,0.9915118,0.0004317518,0.0001505188,0.0002933299],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996602,0.0000739047,0.0003796391,0.001478608,0.0002150577,0.0009371813,0.0001758296,0.00002199991,0.0001157857],"genre_scores_gemma":[0.9992569,0.00004465888,0.0001361981,0.0002354397,0.0002012972,0.00004156382,0.00001994248,0.00003429783,0.0000297137],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004968535,"threshold_uncertainty_score":0.9970702,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01606726015200197,"score_gpt":0.2605646789651991,"score_spread":0.2444974188131971,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}