{"id":"W2735078312","doi":"10.1002/anie.201704922","title":"Rhodium‐Catalyzed Enantioselective Reductive Arylation: Convenient Access to 3,3‐Disubstituted Oxindoles","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada","keywords":"Rhodium; Enantioselective synthesis; Catalysis; Chemistry; Intramolecular force; Combinatorial chemistry; Reactivity (psychology); Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002767942,0.0002810581,0.0002563653,0.0001877366,0.0005237623,0.0005596436,0.0009139756,0.0001737668,0.004208457],"category_scores_gemma":[0.00182858,0.0003039545,0.0001572659,0.0001502654,0.0001886345,0.001480143,0.0003189653,0.0002323176,0.0001499758],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005594813,"about_ca_system_score_gemma":0.000156121,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001755862,"about_ca_topic_score_gemma":0.00005114486,"domain_scores_codex":[0.9978815,0.00001708681,0.0004447274,0.0006565269,0.0007266651,0.0002734419],"domain_scores_gemma":[0.997533,0.0001576184,0.0005199908,0.0006323479,0.0009696214,0.0001874266],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006463301,0.0003415989,0.005786722,0.00007516787,0.000447351,0.0000274129,0.000637919,0.0002962982,0.9430926,0.003801915,0.0413553,0.003491395],"study_design_scores_gemma":[0.001099371,0.000009803894,0.01295207,0.0001362945,0.00005350463,0.00003777512,0.0001003156,0.0001864638,0.9589309,0.002601915,0.02354951,0.0003420612],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4949308,0.000133058,0.2202708,0.01891358,0.01555289,0.001056455,0.001892715,0.0007759634,0.2464738],"genre_scores_gemma":[0.9868363,0.00003523504,0.00136751,0.000309551,0.004322157,0.000233467,0.003258694,0.00004397861,0.003593088],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4919055,"threshold_uncertainty_score":0.9999412,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04290240638463105,"score_gpt":0.3424082985493735,"score_spread":0.2995058921647424,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}