{"id":"W2735337561","doi":"10.1016/j.bbapap.2017.07.005","title":"Unraveling the meaning of chemical shifts in protein NMR","year":2017,"lang":"en","type":"review","venue":"Biochimica et Biophysica Acta (BBA) - Proteins and Proteomics","topic":"Protein Structure and Dynamics","field":"Biochemistry, Genetics and Molecular Biology","cited_by":35,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Alberta","funders":"Alberta Prion Research Institute; Natural Sciences and Engineering Research Council of Canada","keywords":"Meaning (existential); Chemical shift; Chemistry; Epistemology; Philosophy; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0007204774,0.0009239449,0.001672644,0.0001646168,0.0002190002,0.0001877162,0.001359597,0.001060059,0.000003095158],"category_scores_gemma":[0.0002968852,0.0006622523,0.0005823093,0.000230986,0.0005592455,0.00002241863,0.0009858479,0.00102341,0.000003050026],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005133,"about_ca_system_score_gemma":0.0006644535,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009172114,"about_ca_topic_score_gemma":0.00002366579,"domain_scores_codex":[0.9964826,0.0003251422,0.001091861,0.001128005,0.0003400254,0.0006323846],"domain_scores_gemma":[0.9967143,0.00004279178,0.001376508,0.001607243,0.0001116,0.0001475358],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002063825,0.0001547517,7.123668e-7,0.007290198,0.0003944852,0.000009206638,0.0002125623,0.000001399425,0.8531479,0.00142778,0.00002603565,0.1371285],"study_design_scores_gemma":[0.001399616,0.0007472539,0.00001978296,0.01327127,0.0006140671,0.00006814111,0.0000417175,0.0001174346,0.8620974,0.003124097,0.1161376,0.002361607],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.26221,0.7253051,0.000269946,0.0003653708,0.0001497186,0.01061179,0.0004415707,0.00004418243,0.0006022407],"genre_scores_gemma":[0.08577284,0.9019098,0.009043658,0.00008913409,0.0007480317,0.001542945,0.0005387957,0.000229355,0.0001254138],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.1766047,"threshold_uncertainty_score":0.9995829,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03205863247985423,"score_gpt":0.3061453145401062,"score_spread":0.2740866820602519,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}