{"id":"W2735927453","doi":"10.1021/acsnano.7b03540","title":"Emergent Properties of an Organic Semiconductor Driven by its Molecular Chirality","year":2017,"lang":"en","type":"article","venue":"ACS Nano","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":177,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University; Okanagan University College; University of British Columbia, Okanagan Campus; University of British Columbia","funders":"Engineering and Physical Sciences Research Council; Natural Sciences and Engineering Research Council of Canada; Royal Society","keywords":"Helicene; Chirality (physics); Materials science; Molecule; Chemical physics; Organic semiconductor; Fabrication; Transistor; Semiconductor; Symmetry (geometry); Nanotechnology; Optoelectronics; Chemistry; Symmetry breaking; Physics; Organic chemistry; Chiral symmetry breaking; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001035108,0.0001596236,0.0002527869,0.00001382456,0.0002043166,0.00007341267,0.0007927051,0.00008963593,0.001223485],"category_scores_gemma":[0.0002056648,0.0001246214,0.00007249662,0.00001891214,0.00009354862,0.0002197973,0.0001989849,0.00007540535,0.00003299787],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002634603,"about_ca_system_score_gemma":0.00004646341,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000126147,"about_ca_topic_score_gemma":0.0000102314,"domain_scores_codex":[0.9990214,0.00002268616,0.0002854623,0.0002439441,0.0002249206,0.0002015869],"domain_scores_gemma":[0.9985231,0.000007932434,0.0002259514,0.001080036,0.00008101365,0.00008199915],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001765077,0.0001069412,0.000915423,0.0001354262,0.00006380551,0.00000187478,0.0002576725,4.779088e-7,0.9967305,0.00001416163,0.0005929172,0.001163161],"study_design_scores_gemma":[0.0002140897,0.00002996352,0.0002254855,0.00009790309,0.00002888751,0.000003297559,0.00009538177,0.00005549629,0.9965231,0.00004607923,0.002500525,0.0001798095],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943856,0.0008073433,8.576386e-7,0.0003186952,0.00009332599,0.00006508453,0.00002055124,0.00004040508,0.004268133],"genre_scores_gemma":[0.9978923,0.00004842954,0.00007693699,0.00003735179,0.00005171631,0.00001199366,0.000008967023,0.00002763921,0.001844704],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003506657,"threshold_uncertainty_score":0.9996895,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03057489651374547,"score_gpt":0.2434164808716376,"score_spread":0.2128415843578922,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}