{"id":"W2736493752","doi":"10.1039/c7nj01273j","title":"Unpredicted formation of copper(<scp>ii</scp>) complexes containing 2-thiophen-2-yl-1-thiophen-2-ylmethyl-1H-benzoimidazole and their most promising in vitro cytotoxicity in MCF-7 and HeLa cell lines over cisplatin","year":2017,"lang":"en","type":"article","venue":"New Journal of Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Cegep de Saint Jerome","funders":"","keywords":"Chemistry; Sodium azide; HeLa; Copper; Azide; MCF-7; Methanol; In vitro; Cytotoxicity; Halide; Sodium; Stereochemistry; Medicinal chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007719831,0.0002785878,0.0009049698,0.0001212057,0.0001884811,0.00009317758,0.000215562,0.0001993422,0.00001274444],"category_scores_gemma":[0.001079296,0.0002115035,0.00009741247,0.00009521717,0.0001872142,0.0004251759,0.0001584017,0.000573301,2.406747e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006096712,"about_ca_system_score_gemma":0.0001742876,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001267786,"about_ca_topic_score_gemma":0.0000202376,"domain_scores_codex":[0.998105,0.00007546964,0.001000395,0.0002089625,0.0003279761,0.0002822302],"domain_scores_gemma":[0.997869,0.0003535163,0.001084902,0.0002870928,0.0001954687,0.0002100485],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006617166,0.0001111218,0.007147927,0.000611396,0.00003763795,0.00002042284,0.002341792,0.00002009791,0.9864189,0.000002010534,0.0001160517,0.002510926],"study_design_scores_gemma":[0.003941796,0.0002026776,0.02701925,0.001294319,0.00006260823,0.000242623,0.001415577,0.003044605,0.9623343,0.0001207547,0.0002166902,0.0001047846],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943085,0.003466942,0.00004443602,0.0002062557,0.00004877477,0.0002031864,0.00002098852,0.000009058185,0.001691867],"genre_scores_gemma":[0.998257,0.0003299256,0.001007018,0.00007518236,0.0001999298,0.000002709695,0.000009076496,0.00002479213,0.00009438288],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02408459,"threshold_uncertainty_score":0.8624861,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02943701818203509,"score_gpt":0.2597871251188948,"score_spread":0.2303501069368598,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}