{"id":"W2737036370","doi":"10.1002/adsc.201700615","title":"Synthesis of Allenamides and Structurally Related Compounds by a Gold‐Catalyzed Hydride Shift Process","year":2017,"lang":"en","type":"article","venue":"Advanced Synthesis & Catalysis","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Hydride; Combinatorial chemistry; Catalysis; Organic chemistry; Hydrogen","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000267314,0.0005594734,0.001139692,0.0001831411,0.0006000405,0.0001734412,0.001154831,0.0002771995,0.0002576124],"category_scores_gemma":[0.003191851,0.0005470314,0.0003558206,0.0002071741,0.0008075809,0.001017581,0.0002797398,0.0003135164,0.00002896144],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001718672,"about_ca_system_score_gemma":0.00009504224,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007394601,"about_ca_topic_score_gemma":0.0002800045,"domain_scores_codex":[0.9969508,0.00003231378,0.0009190696,0.000972337,0.0005615664,0.0005639144],"domain_scores_gemma":[0.9946336,0.001404623,0.001244586,0.002285165,0.0001702403,0.0002618603],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002257347,0.0002948145,0.004884791,0.000744851,0.002015723,0.00003099385,0.0008736711,0.00009627315,0.8848742,0.0001468788,0.0001670796,0.1056449],"study_design_scores_gemma":[0.0005667675,0.000009581373,0.002965272,0.0003681854,0.001349028,0.00006166966,0.0008618433,0.0003486533,0.9908188,0.001082845,0.0008159006,0.0007514757],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.987535,0.0008185969,0.00003157416,0.0006253091,0.00005610772,0.0001554225,0.0004296641,0.0001854789,0.01016283],"genre_scores_gemma":[0.997879,0.0004182851,0.0004748888,0.000009053895,0.0000349844,0.0002017079,0.0001677015,0.0001025175,0.000711875],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1059445,"threshold_uncertainty_score":0.9996981,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006338871462332014,"score_gpt":0.2490592121734007,"score_spread":0.2427203407110687,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}