{"id":"W2738698464","doi":"10.1039/c7ra06526d","title":"Reaction of sterically encumbered phenols, TEMPO-H, and organocarbonyl insertion reactions with L-AlH<sub>2</sub>(L = HC(MeCNDipp)<sub>2</sub>, Dipp = 2,6-diisopropylphenyl)","year":2017,"lang":"en","type":"article","venue":"RSC Advances","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"Sackville Memorial Hospital; Mount Allison University; Saint Mary's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Steric effects; Chemistry; Phenols; Medicinal chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001733525,0.0004269692,0.000495172,0.00008735286,0.0006274536,0.0001260125,0.0003799819,0.000250519,0.00005708267],"category_scores_gemma":[0.0003354471,0.0004002306,0.0001049849,0.0002236576,0.0003930778,0.001220316,0.0001585833,0.0003878362,0.00001507335],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001499744,"about_ca_system_score_gemma":0.0001167511,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004664555,"about_ca_topic_score_gemma":0.0001638275,"domain_scores_codex":[0.9977456,0.00003080628,0.0006312102,0.0007189658,0.0004812821,0.0003921718],"domain_scores_gemma":[0.9973677,0.0001317267,0.001051368,0.0009577264,0.0002878954,0.0002036127],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002277211,0.0002147674,0.006022573,0.0004173382,0.0001042666,0.00001183717,0.0001422063,0.00001269937,0.9640365,0.00009486225,0.00002297073,0.02869225],"study_design_scores_gemma":[0.001020629,0.00009146681,0.009133715,0.0002339106,0.0001358455,0.00007042062,0.0003421635,0.00006956882,0.9824761,0.0008947037,0.005041577,0.0004899604],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.99279,0.0005394764,0.0004607898,0.0003157362,0.0001539857,0.0001747738,0.00005030667,0.0001787722,0.005336161],"genre_scores_gemma":[0.996977,0.001810911,0.0003999112,0.00002705981,0.0002864315,0.00006069548,0.0001008853,0.00006684889,0.0002702691],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02820229,"threshold_uncertainty_score":0.999845,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01098923030099686,"score_gpt":0.2354614440317054,"score_spread":0.2244722137307086,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}