{"id":"W2738896003","doi":"10.1098/rsta.2017.0014","title":"Halogenated triphenylgallium and -indium in frustrated Lewis pair activations and hydrogenation catalysis","year":2017,"lang":"en","type":"article","venue":"Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Deutsche Forschungsgemeinschaft","keywords":"Frustrated Lewis pair; Lewis acids and bases; Phenylacetylene; Phosphine; Chemistry; Catalysis; Imine; Medicinal chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001208674,0.0001435585,0.0002293255,0.00001590011,0.000415684,0.00008147843,0.0002214645,0.0001081922,0.00002763142],"category_scores_gemma":[0.0001096985,0.0001028354,0.0001019207,0.0001328407,0.0006220432,0.00014307,0.00004262216,0.0002658783,4.487978e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001899667,"about_ca_system_score_gemma":0.00001834664,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003211626,"about_ca_topic_score_gemma":0.000001373841,"domain_scores_codex":[0.9991855,0.000007042011,0.0001860868,0.0002496409,0.0002011764,0.0001705798],"domain_scores_gemma":[0.9994664,0.0001611026,0.00006907912,0.0001878747,0.0000201814,0.00009533743],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002792894,0.001406593,0.003537992,0.002002842,0.0003395708,0.000002196691,0.003133171,0.005184008,0.964012,0.0176038,0.00001231391,0.002737564],"study_design_scores_gemma":[0.0006977066,0.00003806586,0.007556584,0.0001902803,0.0001423389,0.000008893674,0.0002212659,0.4529359,0.4937463,0.04411045,0.000008073397,0.0003441189],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944986,0.0000431258,0.0007849936,0.004313833,0.0000142305,0.00005171378,0.00001283708,0.00003257759,0.000248074],"genre_scores_gemma":[0.9995032,0.00001580717,0.0003780169,0.00001224366,0.00004164131,0.00001015661,9.008778e-7,0.000008105319,0.00002995167],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4702657,"threshold_uncertainty_score":0.4193504,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01683950834065543,"score_gpt":0.2338996017250783,"score_spread":0.2170600933844229,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}