{"id":"W2738945474","doi":"10.1039/c7cc05198k","title":"Triplet state CPL active helicene–dithiolene platinum bipyridine complexes","year":2017,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":86,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nautical Research Society","funders":"","keywords":"Helicene; Enantiopure drug; Platinum; Chirality (physics); Chemistry; Photochemistry; Bipyridine; Acetonitrile; Crystallography; Metal; Excited state; Molecule; Enantioselective synthesis; Organic chemistry; Crystal structure; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001444677,0.0002173496,0.0003311825,0.00002930752,0.001020419,0.0002194916,0.003093548,0.0001051694,0.0006731729],"category_scores_gemma":[0.0006535026,0.000197425,0.0001380738,0.00004282628,0.0005493969,0.0002065373,0.001358643,0.0003808679,0.0001186813],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008604728,"about_ca_system_score_gemma":0.00005345272,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001359658,"about_ca_topic_score_gemma":0.00005308092,"domain_scores_codex":[0.9988126,0.00003373963,0.000390345,0.0002619048,0.0002094131,0.0002920255],"domain_scores_gemma":[0.9942882,0.0005749941,0.0003294677,0.004539049,0.000124654,0.0001436306],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007200291,0.0002525761,0.0004543429,0.0000557432,0.0001202253,9.554567e-7,0.0005476456,9.899117e-7,0.9658684,0.0005396504,0.004126397,0.02796103],"study_design_scores_gemma":[0.0007596835,0.00001072264,0.0006695654,0.0001956123,0.00004710463,0.000009223386,0.0002817319,0.001327564,0.8487904,0.003572786,0.1439428,0.0003928061],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8365579,0.000628181,0.0000272682,0.01017063,0.00006143731,0.0001105282,0.0002618839,0.000193023,0.1519892],"genre_scores_gemma":[0.9943832,0.0003408064,0.003178075,0.0001029323,0.0000995623,0.00007824818,0.0002036595,0.000033812,0.00157975],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1578253,"threshold_uncertainty_score":0.8050758,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06639246863572466,"score_gpt":0.3017131045604006,"score_spread":0.2353206359246759,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}