{"id":"W2738945474","doi":"10.1039/c7cc05198k","title":"Triplet state CPL active helicene–dithiolene platinum bipyridine complexes","year":2017,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":86,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nautical Research Society","funders":"","keywords":"Helicene; Enantiopure drug; Platinum; Chirality (physics); Chemistry; Photochemistry; Bipyridine; Acetonitrile; Crystallography; Metal; Excited state; Molecule; Enantioselective synthesis; Organic chemistry; Crystal structure; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001074667,0.0002300663,0.0002362969,0.0001255233,0.0002213434,0.0005162191,0.000314062,0.0003986713,0.002882099],"category_scores_gemma":[0.0002942659,0.0001280282,0.00006718623,0.0001382745,0.0002281211,0.0002818986,0.0002219897,0.0005596368,0.0006091772],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005000925,"about_ca_system_score_gemma":0.0001353588,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006746076,"about_ca_topic_score_gemma":0.0009713947,"domain_scores_codex":[0.9998385,0.00002292531,0.000010216,0.00003325849,0.00005402753,0.00004110973],"domain_scores_gemma":[0.9998801,0.00002217181,0.00002156708,0.00001645843,0.00002174917,0.00003800132],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001242415,0.00001603187,0.00008359879,0.00004032466,0.000004336653,0.00006811049,0.00003952578,0.00005244421,0.9969283,0.0004210747,0.0002439623,0.001978232],"study_design_scores_gemma":[0.00002323929,0.00009555089,0.0004010703,0.000002974436,0.000004266627,0.00009645701,0.00001203285,0.0003342071,0.9962669,0.00004662315,0.002711558,0.0000050642],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9837734,0.001546952,0.003017631,0.0002718814,0.00008788228,0.00004440531,0.0003034894,0.0002039894,0.01075046],"genre_scores_gemma":[0.994908,0.0002755204,0.0008184888,0.00004194376,0.00001042601,0.0000119602,0.0002044875,0.00002670908,0.003702388],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002882099,"threshold_uncertainty_score":0.009641588,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06639246863572466,"score_gpt":0.3017131045604006,"score_spread":0.2353206359246759,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}