{"id":"W2738950438","doi":"10.1002/cjce.22945","title":"Kinetics study and process simulation of transesterification of ethylene glycol with methyl acetate for ethylene glycol diacetate","year":2017,"lang":"en","type":"article","venue":"The Canadian Journal of Chemical Engineering","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Science Foundation of Tianjin City; Nankai University","keywords":"Transesterification; Ethylene glycol; Reactive distillation; Methyl acetate; Chemistry; Solvent; Catalysis; Ion-exchange resin; Kinetics; Fractionating column; Distillation; Organic chemistry; Chromatography; Chemical engineering","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001868313,0.0001280661,0.0003053033,0.00004954413,0.00007890051,0.00003789582,0.000272431,0.00008564226,0.00001268116],"category_scores_gemma":[0.0003460863,0.0000901341,0.00007439867,0.00005160176,0.0001188575,0.00009553164,0.00000778228,0.0002025978,5.070769e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005442643,"about_ca_system_score_gemma":0.00009148113,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000243131,"about_ca_topic_score_gemma":0.0001646152,"domain_scores_codex":[0.9991667,0.000006400751,0.000394829,0.0001028404,0.0001656296,0.0001635713],"domain_scores_gemma":[0.9986662,0.0002384575,0.0004251127,0.0002384942,0.000240222,0.0001914966],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001102814,0.00004551895,0.0003428695,0.0002494113,0.0001226732,0.000001855697,0.0007864165,0.02429991,0.9717264,0.00000570332,0.000001045618,0.00230794],"study_design_scores_gemma":[0.0008818673,0.00007197915,0.0005735176,0.0001833351,0.0002005901,0.00001533328,0.0001050924,0.008130685,0.9895304,0.00004579715,0.0001483263,0.0001131158],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982208,0.000136697,0.001111674,0.0002582892,0.00002950538,0.0001672127,0.00003045834,0.000003775724,0.00004155611],"genre_scores_gemma":[0.9993892,0.000005838145,0.0004880778,0.000003027848,0.00006444503,0.00001275581,0.000002296776,0.00002278862,0.00001155253],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01780399,"threshold_uncertainty_score":0.3675562,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0209341797760991,"score_gpt":0.2622069899898148,"score_spread":0.2412728102137157,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}