{"id":"W2739326696","doi":"10.1002/anie.201706798","title":"Fluorinative Rearrangements of Substituted Phenylallenes Mediated by (Difluoroiodo)toluene: Synthesis of α‐(Difluoromethyl)styrenes","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":83,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Allene; Toluene; Chemistry; Regioselectivity; Yield (engineering); Fluorine; Medicinal chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005048994,0.0002734537,0.0004208743,0.0001149403,0.0001943728,0.00002746967,0.0009548734,0.0003604218,0.003295136],"category_scores_gemma":[0.002114717,0.0002874332,0.0001630526,0.0001008537,0.0005701166,0.0003935148,0.0002119026,0.0003496914,0.00003376669],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001478988,"about_ca_system_score_gemma":0.00007887356,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001561874,"about_ca_topic_score_gemma":0.00001148902,"domain_scores_codex":[0.9981249,0.00007545568,0.0006232457,0.0003888754,0.0005179131,0.00026961],"domain_scores_gemma":[0.9972179,0.0006740013,0.0008948302,0.0004445345,0.0006373835,0.0001313396],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002884971,0.0004612276,0.006470178,0.0001304037,0.0006651898,0.0000109285,0.0001740355,0.000005972957,0.9666622,0.0001245636,0.02168564,0.003321182],"study_design_scores_gemma":[0.001397005,0.00003420328,0.003572709,0.00009587153,0.0001572288,0.000007665057,0.00009106681,0.00007073468,0.9731451,0.0002906341,0.02090649,0.0002313147],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9638394,0.0007400868,0.0002282189,0.002387511,0.004115178,0.0003288251,0.002693833,0.0001014512,0.02556557],"genre_scores_gemma":[0.9964373,0.0008700515,0.0002744419,0.00007524205,0.0007206896,0.00008115296,0.0006403783,0.00003222753,0.0008684957],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03259799,"threshold_uncertainty_score":0.9999578,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0640374706250518,"score_gpt":0.3925381692487493,"score_spread":0.3285006986236975,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}