{"id":"W2740607114","doi":"10.1139/cjc-2017-0155","title":"Pressure-selected reactivity between 2-butyne and water induced by two-photon excitation","year":2017,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Ontario Ministry of Research and Innovation","keywords":"Chemistry; Dissociation (chemistry); Photochemistry; Catalysis; Kinetics; Isomerization; Polymerization; Reactivity (psychology); Fourier transform infrared spectroscopy; Infrared; Molecule; Physical chemistry; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001706676,0.0004812064,0.0001984915,0.0001177854,0.0001612305,0.0002217944,0.0003231286,0.0002991057,0.001456822],"category_scores_gemma":[0.0003388778,0.0002280642,0.0001570968,0.0001736693,0.0002885011,0.0004619212,0.0002843243,0.0004951301,0.0001613097],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002254142,"about_ca_system_score_gemma":0.0001660345,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004898293,"about_ca_topic_score_gemma":0.0007848308,"domain_scores_codex":[0.9998554,0.00001544854,0.000004671486,0.00003855483,0.00004222102,0.00004373855],"domain_scores_gemma":[0.9998627,0.00006862242,0.00003573213,0.00001014148,0.00001052225,0.00001224059],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006277196,0.000008662138,0.00007399908,0.00003370506,0.000003186078,0.00004423843,0.00003102569,0.00007261938,0.9990759,0.00006805318,0.000017873,0.0005079278],"study_design_scores_gemma":[0.000007542342,0.0001050314,0.0007324549,0.000001500802,0.000003115183,0.00003115597,0.0000104999,0.0004158428,0.9984424,0.00002164255,0.0002259434,0.000003023035],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973474,0.0002613492,0.001217116,0.00002664674,0.000008956936,0.00001862759,0.00008143122,0.00003366671,0.001004857],"genre_scores_gemma":[0.998037,0.0002785583,0.0007399588,0.00001168315,0.000004523833,0.0000177482,0.0000823088,0.00001719889,0.0008110289],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001456822,"threshold_uncertainty_score":0.004873574,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01442377331909525,"score_gpt":0.2374580761109383,"score_spread":0.2230343027918431,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}