{"id":"W2740796940","doi":"10.1002/anie.201705903","title":"Photochemical Dual‐Catalytic Synthesis of Alkynyl Sulfides","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":81,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada; Centre in Green Chemistry and Catalysis","keywords":"Chemistry; Catalysis; Carbazole; Photocatalysis; Sulfide; Combinatorial chemistry; Photochemistry; Steric effects; Functional group; Organic synthesis; Continuous flow; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009246194,0.000337412,0.0002111134,0.0001660014,0.0001545523,0.0001838146,0.000227369,0.0001924485,0.001011493],"category_scores_gemma":[0.00006338761,0.0001443785,0.0001752661,0.0001488833,0.0001577876,0.0001904861,0.0002550558,0.0003272466,0.0003773392],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000329947,"about_ca_system_score_gemma":0.0002500971,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004499146,"about_ca_topic_score_gemma":0.001324964,"domain_scores_codex":[0.9999293,0.000005068841,0.00000584146,0.00002066006,0.00001944335,0.00001968374],"domain_scores_gemma":[0.999963,0.000004211418,0.000009460089,0.000004506152,0.000007706886,0.00001101389],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002363217,0.00001492984,0.00005534608,0.00004995188,0.000005533233,0.00008790956,0.00002172984,0.0001690693,0.9957994,0.0005379385,0.00008951109,0.003145074],"study_design_scores_gemma":[0.000007059766,0.0001062096,0.0002624849,0.000002197043,0.00000604976,0.00008511664,0.000007312055,0.0004895991,0.9962749,0.00005506324,0.002700806,0.000003318104],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9657242,0.002275736,0.02016556,0.0001444156,0.0001548341,0.00008784208,0.0004662696,0.0003060618,0.01067501],"genre_scores_gemma":[0.9847061,0.001289497,0.009274156,0.00003039071,0.00001333286,0.00003679451,0.0002391915,0.00003944915,0.004371119],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001011493,"threshold_uncertainty_score":0.003383756,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02038995975101972,"score_gpt":0.2831676648459854,"score_spread":0.2627777050949657,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}