{"id":"W2740796940","doi":"10.1002/anie.201705903","title":"Photochemical Dual‐Catalytic Synthesis of Alkynyl Sulfides","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":81,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada; Centre in Green Chemistry and Catalysis","keywords":"Chemistry; Catalysis; Carbazole; Photocatalysis; Sulfide; Combinatorial chemistry; Photochemistry; Steric effects; Functional group; Organic synthesis; Continuous flow; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002113357,0.0002118864,0.0002670946,0.00009165193,0.0001362299,0.00009843856,0.0007462553,0.0002112689,0.002642035],"category_scores_gemma":[0.002397682,0.0002191351,0.0002029574,0.00003118158,0.0002884953,0.0004203088,0.0001646577,0.0001810036,0.00004813525],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001717112,"about_ca_system_score_gemma":0.00005311989,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001317962,"about_ca_topic_score_gemma":0.000006623226,"domain_scores_codex":[0.9984695,0.000006971365,0.0004042041,0.0003609724,0.0005514447,0.0002069136],"domain_scores_gemma":[0.9980126,0.0003947481,0.0004980914,0.0007283805,0.0002827091,0.00008345991],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007473528,0.0001486229,0.001729314,0.0000748243,0.0001104002,0.00001470434,0.00003450792,3.276674e-7,0.9856497,0.0001719949,0.009532901,0.002457992],"study_design_scores_gemma":[0.0002727478,0.000007292487,0.0004860186,0.0003351911,0.00005358667,0.00002180437,0.00005289917,0.00002948372,0.9910303,0.001583879,0.005912303,0.000214501],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8067657,0.00005419071,0.0003456745,0.001243618,0.0004940768,0.0001104897,0.0004892097,0.0002534342,0.1902436],"genre_scores_gemma":[0.9969934,0.00006788068,0.0008018678,0.00005537304,0.001108714,0.000101831,0.0002363586,0.00003523674,0.0005994015],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1902277,"threshold_uncertainty_score":0.9982697,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02038995975101972,"score_gpt":0.2831676648459854,"score_spread":0.2627777050949657,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}