{"id":"W2744448583","doi":"10.1021/acscatal.7b01293","title":"Amidate Complexes of Tantalum and Niobium for the Hydroaminoalkylation of Unactivated Alkenes","year":2017,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung; Boehringer Ingelheim","keywords":"Steric effects; Alkene; Chemistry; Catalysis; Amine gas treating; Tantalum; Catalytic cycle; Acetonitrile; Metallacycle; Electronic effect; Photochemistry; Reaction mechanism; Niobium; Medicinal chemistry; Combinatorial chemistry; Organic chemistry; X-ray crystallography","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001729511,0.0002958076,0.0002288407,0.0002312014,0.0001592043,0.0002854896,0.000431497,0.0002594799,0.001016612],"category_scores_gemma":[0.0002740922,0.0001771231,0.0002127266,0.0001563883,0.0001680713,0.000236575,0.0001846968,0.0002803884,0.0004390177],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004087445,"about_ca_system_score_gemma":0.0002250427,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007326056,"about_ca_topic_score_gemma":0.004043979,"domain_scores_codex":[0.999853,0.00002035295,0.00002026249,0.0000236879,0.00005051867,0.00003208639],"domain_scores_gemma":[0.9998939,0.00001452089,0.00002969553,0.00001628433,0.00002664791,0.00001892122],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000121969,0.00001978721,0.0001543308,0.0001133865,0.000009521569,0.00007394718,0.00003626217,0.0001153735,0.9955752,0.0004775414,0.0000701848,0.003232531],"study_design_scores_gemma":[0.000009510364,0.0002028778,0.0004697141,0.000004788984,0.00001187593,0.0001178476,0.000012416,0.0003128804,0.9958498,0.00002985125,0.002974205,0.000004181044],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9793115,0.002444131,0.007324823,0.0001288292,0.00006255947,0.0001209493,0.0002830058,0.0001578226,0.01016647],"genre_scores_gemma":[0.9888142,0.001072026,0.006139812,0.00003231825,0.00001054317,0.00003181766,0.0002568558,0.00003406168,0.003608458],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001016612,"threshold_uncertainty_score":0.003400922,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02003049446396363,"score_gpt":0.2721981787428838,"score_spread":0.2521676842789202,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}