{"id":"W2745660004","doi":"10.1021/acs.jnatprod.7b00305","title":"Xylomexicanins I and J: Limonoids with Unusual B/C Rings from <i>Xylocarpus granatum</i>","year":2017,"lang":"en","type":"article","venue":"Journal of Natural Products","topic":"Phytochemical compounds biological activities","field":"Biochemistry, Genetics and Molecular Biology","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Japan Society for the Promotion of Science; Natural Science Foundation of Hebei Province; National Natural Science Foundation of China","keywords":"Limonoid; Stereochemistry; Traditional medicine; Meliaceae; Chemistry; Triterpene; Terpene; Mangrove; Terpenoid; Biology; Botany; Medicine; Ecology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001381367,0.0001610007,0.0002502506,0.00002686181,0.0001664097,0.00009719757,0.0003871347,0.0001045518,0.000001795946],"category_scores_gemma":[0.0005157545,0.0001014893,0.00005570925,0.00003311566,0.0003209524,0.00002848988,0.0001835092,0.0003579844,7.136505e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001373611,"about_ca_system_score_gemma":0.00005671879,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002047847,"about_ca_topic_score_gemma":0.000009906923,"domain_scores_codex":[0.9991603,0.0000323997,0.0001905864,0.0002605262,0.0001685309,0.0001876837],"domain_scores_gemma":[0.9989503,0.00002277432,0.0003903157,0.0003184564,0.0002280238,0.00009013976],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005390735,0.00004696977,0.00466602,0.00001019221,0.00009418471,0.00002430491,0.00001595106,7.027299e-7,0.9911898,0.00001789629,0.001383536,0.002011399],"study_design_scores_gemma":[0.0007505634,0.0008033781,0.04163409,0.00003790463,0.00003377664,0.0001502373,0.00002229923,0.000003755707,0.9489788,0.0009427643,0.006451447,0.0001909693],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995057,0.00281808,0.00001913063,0.001469854,0.0002659862,0.0000668838,0.00001247448,0.000004789204,0.000285829],"genre_scores_gemma":[0.9973934,0.0001615961,0.001109523,0.0002095094,0.0009500508,0.000001581424,0.00001005432,0.00001174928,0.0001525249],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04221096,"threshold_uncertainty_score":0.4138613,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008501156411136187,"score_gpt":0.2288272136664826,"score_spread":0.2203260572553464,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}