{"id":"W2746123056","doi":"10.1055/s-0036-1588540","title":"Catalytic Deuteration of Aldehydes with D2O","year":2017,"lang":"en","type":"article","venue":"Synlett","topic":"Chemical Reactions and Isotopes","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Deuterium; Catalysis; Combinatorial chemistry; Heavy water; Organic chemistry; Computational chemistry; Nuclear physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000127197,0.00007668253,0.0001187642,0.00002406874,0.0002332856,0.00002205554,0.0001681139,0.00009252979,0.0002617277],"category_scores_gemma":[0.00007927246,0.00005924553,0.00003436451,0.00002514304,0.0001966637,0.0001285455,0.00003739197,0.0001917044,0.00005876413],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001662437,"about_ca_system_score_gemma":0.00002890937,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006542875,"about_ca_topic_score_gemma":0.00003682692,"domain_scores_codex":[0.9995316,0.00002309307,0.0001308424,0.0001173898,0.00006531782,0.0001318177],"domain_scores_gemma":[0.9994252,0.00008034264,0.0001302648,0.0002510998,0.00005021485,0.00006284211],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005692034,0.0005949237,0.07223956,0.0001614906,0.0004322006,0.00005517575,0.0006287273,0.000111836,0.7895756,0.008673704,0.01827138,0.1086861],"study_design_scores_gemma":[0.0008935076,0.0001013411,0.01099349,0.00002555047,0.0001055951,0.00002457351,0.00003069075,0.0004642842,0.7410712,0.000386801,0.2457563,0.0001467626],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9449395,0.00009271129,0.0001745107,0.00148971,0.000259849,0.0001419877,0.00001872864,0.00002627761,0.0528567],"genre_scores_gemma":[0.9977846,0.00004359608,0.0002739173,0.0002997712,0.0001094498,0.00001344204,0.00001078703,0.000007580156,0.001456882],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2274849,"threshold_uncertainty_score":0.2865734,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1278757767551657,"score_gpt":0.4588125908553912,"score_spread":0.3309368141002255,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}