{"id":"W2750267236","doi":"10.1021/acs.organomet.7b00396","title":"Nickel and Platinum PCP Pincer Complexes Incorporating an Acyclic Diaminoalkyl Central Moiety Connecting Imidazole or Pyrazole Rings","year":2017,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Moiety; Pincer movement; Imidazole; Deprotonation; Carbene; Pincer ligand; Platinum; Ligand (biochemistry); Nickel; Pyrazole; Chelation; Medicinal chemistry; Hydride; Cobalt; Stereochemistry; Reactivity (psychology); Combinatorial chemistry; Organic chemistry; Metal; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004078379,0.0005678741,0.0008082174,0.0001108294,0.001769364,0.001042414,0.001130885,0.000226253,0.01346131],"category_scores_gemma":[0.0008064393,0.0005122427,0.0001993697,0.0001888156,0.000407275,0.001018033,0.0009019512,0.0004105698,0.00005761018],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001638268,"about_ca_system_score_gemma":0.0001166895,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000393525,"about_ca_topic_score_gemma":0.0008014109,"domain_scores_codex":[0.9969443,0.00003406192,0.0007193551,0.0009419058,0.0005385735,0.0008217745],"domain_scores_gemma":[0.9966787,0.0002380333,0.0008529608,0.001635782,0.0001285618,0.0004659868],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001058878,0.0004875901,0.04525422,0.0004030714,0.0005339767,0.000054435,0.002225246,0.00003044009,0.8279067,0.001980069,0.00005212687,0.1209663],"study_design_scores_gemma":[0.005282235,0.0002840439,0.3558724,0.0005545849,0.001257862,0.0003980599,0.0127815,0.01687611,0.5351508,0.002657672,0.06319241,0.005692339],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9888366,0.0002436777,0.0001603521,0.000252591,0.0001242015,0.0001322117,0.0001264147,0.0002230853,0.00990085],"genre_scores_gemma":[0.9950396,0.0000994564,0.001898603,0.00008135282,0.0004727999,0.00002064419,0.0001101584,0.0001356248,0.002141756],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3106182,"threshold_uncertainty_score":0.9999946,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03359920992140142,"score_gpt":0.2692739433093035,"score_spread":0.2356747333879021,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}