{"id":"W2750575060","doi":"10.1021/acscatal.7b02415","title":"Rethinking the Dehydrogenative Amide Synthesis","year":2017,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":64,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Hemiaminal; Dehydrogenation; Catalysis; Aldehyde; Chemistry; Amide; Acetaldehyde; Combinatorial chemistry; Organic chemistry; Photochemistry; Ethanol","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["sts"],"consensus_categories":[],"category_scores_codex":[0.0005258683,0.000224771,0.0003039906,0.0001207556,0.00172282,0.0003320875,0.001630341,0.0001427648,0.0008959874],"category_scores_gemma":[0.002464307,0.0001613174,0.0003270873,0.000312232,0.0002795978,0.0003129921,0.0003629618,0.0002648844,0.0004009608],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001139758,"about_ca_system_score_gemma":0.00004707692,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004020053,"about_ca_topic_score_gemma":0.0001273433,"domain_scores_codex":[0.9983298,0.00003379316,0.0003205063,0.000430791,0.0005606389,0.0003244583],"domain_scores_gemma":[0.9966831,0.0004506204,0.0004754008,0.002154548,0.0001300961,0.0001061985],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001467988,0.000619648,0.03873447,0.0002222836,0.009864945,0.0002923278,0.01765601,0.0003209093,0.1318573,0.007729772,0.009449591,0.7831059],"study_design_scores_gemma":[0.0002043087,0.000002916888,0.001014343,0.00002612155,0.0007774953,0.00001492901,0.0007140632,0.001025218,0.9821001,0.001664138,0.01209162,0.0003647633],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8567064,0.0004241556,0.0002067385,0.003060457,0.00008483104,0.0000717377,0.00004633005,0.0001731977,0.1392261],"genre_scores_gemma":[0.9950719,0.00009325746,0.00009813543,0.000207522,0.0001619886,0.00007895567,0.00006321262,0.00003295357,0.004192099],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.8502428,"threshold_uncertainty_score":0.9995768,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02508856218007537,"score_gpt":0.2615332576091459,"score_spread":0.2364446954290705,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}