{"id":"W2750618251","doi":"10.1039/c7cp04078d","title":"Separate mechanisms of ion oligomerization tune the physicochemical properties of n-butylammonium acetate: cation-base clusters vs. anion-acid dimers","year":2017,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Canada Excellence Research Chairs, Government of Canada","keywords":"Chemistry; Ion; Base (topology); Acid–base reaction; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001193089,0.0002315137,0.0001021345,0.0001527765,0.0001593956,0.0003571869,0.0002386482,0.0003321008,0.002514578],"category_scores_gemma":[0.0002171745,0.0001529556,0.0001252363,0.00007372395,0.0001824332,0.0003425074,0.0002187158,0.0003171521,0.0005966366],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002100645,"about_ca_system_score_gemma":0.0001309529,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003324147,"about_ca_topic_score_gemma":0.0008026719,"domain_scores_codex":[0.9999069,0.00001037221,0.000005723826,0.00003321657,0.00002196742,0.00002188575],"domain_scores_gemma":[0.9999158,0.00002301352,0.00001822872,0.000007037442,0.00001664461,0.00001918489],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004633613,0.000008416679,0.00008881316,0.00002347487,0.000002701321,0.000009268825,0.00001928777,0.00006485489,0.9987877,0.0001537009,0.00003833674,0.0007571228],"study_design_scores_gemma":[0.000006698302,0.00005347025,0.0008416814,0.000003031787,0.000006253932,0.00003161308,0.00001705175,0.001410924,0.9966009,0.00005338496,0.0009715404,0.000003404013],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9900477,0.0007201499,0.004798976,0.00009593728,0.00004315342,0.00005169948,0.0001743131,0.0001326993,0.003935374],"genre_scores_gemma":[0.9949799,0.000207794,0.002304602,0.00003732708,0.000006767604,0.00003530866,0.0001133618,0.00001909824,0.002295806],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002514578,"threshold_uncertainty_score":0.008412063,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01595542643598346,"score_gpt":0.2344810813535205,"score_spread":0.2185256549175371,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}