{"id":"W2753743093","doi":"10.1039/c7sc03768f","title":"The photochemical alkylation and reduction of heteroarenes","year":2017,"lang":"en","type":"article","venue":"Chemical Science","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":103,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"American Chemical Society Petroleum Research Fund; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; University of Ottawa","keywords":"Alkylation; Chemistry; Combinatorial chemistry; Surface modification; Molecule; Reduction (mathematics); Photochemistry; Organic chemistry; Catalysis; Mathematics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001238201,0.000180609,0.00008198974,0.0001191538,0.0001238367,0.00009833965,0.000293407,0.0002741116,0.001413131],"category_scores_gemma":[0.000131871,0.00007487649,0.0001352049,0.0001043977,0.0001867998,0.0002552032,0.0002271282,0.0003645063,0.0004130412],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001856917,"about_ca_system_score_gemma":0.0001238217,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002406133,"about_ca_topic_score_gemma":0.0006560217,"domain_scores_codex":[0.9999006,0.0000103734,0.00000470328,0.00002758328,0.00003090683,0.00002590498],"domain_scores_gemma":[0.9999547,0.00001056307,0.00001266056,0.00001050446,0.000006836942,0.000004800962],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002160036,0.00001025668,0.0000736741,0.00005431637,0.000004340725,0.00004812544,0.00003597138,0.0001537121,0.9944654,0.0008943357,0.00008405393,0.004154203],"study_design_scores_gemma":[0.000003233673,0.0001068277,0.0003765033,0.000002435515,0.000003112754,0.0001382393,0.000008915253,0.0003418671,0.9959947,0.000109858,0.002911086,0.000003274425],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9512331,0.003890027,0.02598319,0.0002288099,0.00006282685,0.00007356933,0.0002739703,0.0001573189,0.01809717],"genre_scores_gemma":[0.9904492,0.00132635,0.00495842,0.00005863887,0.0000161987,0.00001990169,0.0001030019,0.00001478178,0.003053464],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001413131,"threshold_uncertainty_score":0.004727423,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01632832551352564,"score_gpt":0.2918541821135713,"score_spread":0.2755258566000456,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}