{"id":"W2754582728","doi":"10.1021/acs.organomet.7b00446","title":"Catalysis of Cross-Coupling and Homocoupling Reactions of Aryl Halides Utilizing Ni(0), Ni(I), and Ni(II) Precursors; Ni(0) Compounds as the Probable Catalytic Species but Ni(I) Compounds as Intermediates and Products","year":2017,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":65,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Bromobenzene; Catalysis; Aryl; Oxidative addition; Chlorobenzene; Transmetalation; Biphenyl; Nickel; Halide; Coupling reaction; Medicinal chemistry; Heck reaction; Iodide; Phenylboronic acid; Palladium; Inorganic chemistry; Photochemistry; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002656765,0.0006187335,0.0003214123,0.0003151486,0.0001935801,0.0002561439,0.0006560726,0.0004692385,0.001148932],"category_scores_gemma":[0.0002517605,0.0003341617,0.0002677275,0.0002563723,0.0002430147,0.000418754,0.0005447245,0.000360721,0.0003378683],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004432358,"about_ca_system_score_gemma":0.0001934725,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008172293,"about_ca_topic_score_gemma":0.001444381,"domain_scores_codex":[0.9996434,0.00006678163,0.0000301287,0.00006965177,0.0001064527,0.00008356347],"domain_scores_gemma":[0.9999326,0.00001021655,0.00001715237,0.00001107998,0.00001212059,0.00001670507],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001255132,0.00003664386,0.0002085796,0.0002011288,0.00002881973,0.00008154147,0.00006983464,0.0001937464,0.9952443,0.0004557575,0.00007523839,0.003278849],"study_design_scores_gemma":[0.000007614494,0.00008893688,0.0004096017,0.000003121405,0.00001259056,0.00007456667,0.00001421304,0.0005656918,0.9981171,0.00002570691,0.0006771222,0.000003690943],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9805414,0.003481596,0.006380327,0.00006740402,0.00004235562,0.00007848886,0.0001615261,0.0001296459,0.009117276],"genre_scores_gemma":[0.9935702,0.001307289,0.002909294,0.0000192707,0.00001013342,0.00004903784,0.0002123742,0.00001111663,0.001911136],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001148932,"threshold_uncertainty_score":0.003843606,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0285443217057063,"score_gpt":0.2871952368225625,"score_spread":0.2586509151168562,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}