{"id":"W2755375837","doi":"10.1039/c7qo00750g","title":"Ultra-fast Suzuki and Heck reactions for the synthesis of styrenes and stilbenes using arenediazonium salts as super-electrophiles","year":2017,"lang":"en","type":"article","venue":"Organic Chemistry Frontiers","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nautical Research Society","funders":"Université de Nantes; Tomsk State University; Centre National de la Recherche Scientifique; Deutsche Forschungsgemeinschaft; Institut Universitaire de France; Tomsk Polytechnic University","keywords":"Electrophile; Chemistry; Heck reaction; Combinatorial chemistry; Potassium; Organic chemistry; Catalysis; Palladium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008368989,0.001332544,0.0003706524,0.0007255591,0.000404296,0.0004228739,0.0009325436,0.0005077019,0.003490679],"category_scores_gemma":[0.000469456,0.0004906607,0.0004605194,0.0004903133,0.0003834482,0.001046806,0.0007237418,0.001308602,0.001899483],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004281331,"about_ca_system_score_gemma":0.0005819333,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004676631,"about_ca_topic_score_gemma":0.001407225,"domain_scores_codex":[0.9997306,0.00004453283,0.00002451333,0.00004139065,0.00007962342,0.00007925068],"domain_scores_gemma":[0.9998325,0.00003158667,0.0000292445,0.00003837846,0.00002576942,0.00004250706],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002776345,0.0001483254,0.0006025471,0.0007827688,0.00008836902,0.0006926794,0.0002819859,0.00108814,0.9100773,0.01597011,0.001338004,0.06865203],"study_design_scores_gemma":[0.000039158,0.0005330566,0.0007557496,0.00002187329,0.00006688741,0.0007324819,0.00005641247,0.001491961,0.9731339,0.001562315,0.02154856,0.00005746206],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.595987,0.03632687,0.3266921,0.0007603072,0.0007035687,0.0005209508,0.000996185,0.001773959,0.03623907],"genre_scores_gemma":[0.8915302,0.01598514,0.0752223,0.0001147369,0.0001690588,0.0002910047,0.0007685858,0.0001515134,0.01576748],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003490679,"threshold_uncertainty_score":0.0116775,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01288899621054566,"score_gpt":0.2540316838261617,"score_spread":0.2411426876156161,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}