{"id":"W2756368038","doi":"10.1021/acssuschemeng.7b01668","title":"Synthesis of Fully Biobased Polyesters from Plant Oil","year":2017,"lang":"en","type":"article","venue":"ACS Sustainable Chemistry & Engineering","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Alberta Innovates Bio Solutions","keywords":"Gel permeation chromatography; Polyester; Differential scanning calorimetry; Fourier transform infrared spectroscopy; Chemistry; Gas chromatography; Condensation polymer; Thermogravimetric analysis; Organic chemistry; Materials science; Polymer chemistry; Chemical engineering; Chromatography; Catalysis; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000230561,0.0004780019,0.0006029458,0.00003379532,0.0002367869,0.0001588842,0.00136816,0.000376806,0.001445985],"category_scores_gemma":[0.003540467,0.0005448168,0.0001861873,0.00008818231,0.00016372,0.0002070835,0.000453945,0.0003764431,0.000006419017],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003289493,"about_ca_system_score_gemma":0.0001984545,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003697767,"about_ca_topic_score_gemma":3.448465e-7,"domain_scores_codex":[0.9976419,0.000008188597,0.0005325934,0.0006171958,0.0003790397,0.0008210647],"domain_scores_gemma":[0.9964825,0.0005212859,0.0004210257,0.002174463,0.0001410646,0.0002596714],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000389636,0.00005908735,0.0004565157,0.002014016,0.000146888,0.0001849576,0.00009691485,0.0001057544,0.9951301,0.00003135741,0.00006789243,0.001667588],"study_design_scores_gemma":[0.0004722281,0.000002688848,0.00009031147,0.0003561709,0.0001190027,0.00003386264,0.001081579,0.0005382775,0.9898059,0.00003758933,0.006935889,0.0005265262],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9754809,0.0003806814,0.000303779,0.0002195141,0.00009290938,0.00003216576,0.0002049248,0.0002497298,0.02303541],"genre_scores_gemma":[0.9902954,0.00006351653,0.002671846,0.000006668928,0.000362367,0.00004646596,0.00004736276,0.0001112759,0.006395142],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01664026,"threshold_uncertainty_score":0.9997003,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007468119978367175,"score_gpt":0.2155577298611848,"score_spread":0.2080896098828177,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}