{"id":"W2756466793","doi":"10.1021/acs.inorgchem.7b01984","title":"Boron Difluoride Adducts of a Flexidentate Pyridine-Substituted Formazanate Ligand: Property Modulation via Protonation and Coordination Chemistry","year":2017,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Western University; Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Research, Innovation and Science; Canada Foundation for Innovation","keywords":"Chemistry; Protonation; Adduct; Pyridine; Coordination complex; Ligand (biochemistry); Medicinal chemistry; Photochemistry; Boron; Bromide; Trifluoromethanesulfonate; Inorganic chemistry; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003246727,0.0002195987,0.0002834621,0.00001472295,0.0002911706,0.000211483,0.0003926858,0.000158522,0.0002790164],"category_scores_gemma":[0.0002514302,0.0001758512,0.00003885796,0.00004573599,0.0002096175,0.0008566261,0.0001926504,0.0000860759,0.00002381249],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009302007,"about_ca_system_score_gemma":0.00009203716,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002183781,"about_ca_topic_score_gemma":0.000006957152,"domain_scores_codex":[0.9985428,0.00001409247,0.0004623299,0.0003968877,0.0003248888,0.0002590217],"domain_scores_gemma":[0.9984908,0.00001272481,0.0006044022,0.0005515605,0.0002482024,0.00009227036],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008784983,0.00005920987,0.002402368,0.0005202651,0.000009773127,0.000004257959,0.0001639881,0.0000042479,0.9958025,0.000004090158,0.00007977181,0.0008616644],"study_design_scores_gemma":[0.0008441283,0.00001255167,0.007906422,0.0001313058,0.00002943533,0.00002281158,0.00003218411,0.001323544,0.9892344,0.0001390852,0.00009683445,0.0002272853],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984892,0.00003981819,0.0001092084,0.0002257394,0.0001921496,0.0004602297,0.00003385151,0.00007782873,0.0003719944],"genre_scores_gemma":[0.9988912,0.00002862864,0.0001246896,0.00001000157,0.0002081898,0.00005424433,0.00007843093,0.00002332436,0.0005813107],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006568101,"threshold_uncertainty_score":0.7171003,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01234827950799746,"score_gpt":0.2422713963923432,"score_spread":0.2299231168843457,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}