{"id":"W2757800029","doi":"10.1021/acs.inorgchem.7b02048","title":"Syntheses and Characterization of W(NC<sub>6</sub>F<sub>5</sub>)F<sub>5</sub><sup>–</sup> and W<sub>2</sub>(NC<sub>6</sub>F<sub>5</sub>)<sub>2</sub>F<sub>9</sub><sup>–</sup> Salts and Computational Studies of the W(NR)F<sub>5</sub><sup>–</sup> (R = H, F, CH<sub>3</sub>, CF<sub>3</sub>, C<sub>6</sub>H<sub>5</sub>, C<sub>6</sub>F<sub>5</sub>) and W<sub>2</sub>(NC<sub>6</sub>F<sub>5</sub>)<sub>2</sub>F<sub>9</sub><sup>–</sup> Anions","year":2017,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada; Compute Canada; Canada Foundation for Innovation; Government of Canada; Western Canada Research Grid; University of Lethbridge","keywords":"Chemistry; Salt (chemistry); Ligand (biochemistry); Raman spectroscopy; Nuclear magnetic resonance spectroscopy; Crystallography; Crystal structure; Tungstate; Ion; Stereochemistry; Physical chemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001914372,0.0002881728,0.0002616487,0.0001405301,0.0002397964,0.0002742444,0.0003950619,0.0003858471,0.002246078],"category_scores_gemma":[0.0002985126,0.0001791408,0.0001867854,0.0002011453,0.0001593214,0.0002942042,0.0002138392,0.0003495534,0.0007658508],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003503531,"about_ca_system_score_gemma":0.0006013414,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001623211,"about_ca_topic_score_gemma":0.004341769,"domain_scores_codex":[0.9999197,0.000004094683,0.000008770015,0.00001866761,0.00003845798,0.00001027631],"domain_scores_gemma":[0.9999204,0.000005900072,0.00002443884,0.0000135166,0.00002468531,0.00001113867],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003195929,0.00001105202,0.0001238056,0.0001006103,0.000003280603,0.00004786156,0.00003226449,0.0003594385,0.9952564,0.0003529008,0.0001717103,0.003508708],"study_design_scores_gemma":[0.000006524772,0.0001042921,0.0007390833,0.000005711593,0.000006269823,0.00007476677,0.00002253019,0.0006744778,0.9903468,0.00005181576,0.007958608,0.000009056348],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9572842,0.001743048,0.02763617,0.0002036869,0.00008051351,0.0005593288,0.002262197,0.000270127,0.009960646],"genre_scores_gemma":[0.9124502,0.002758485,0.05832795,0.0001044431,0.00002150005,0.0004886339,0.002932796,0.0001551567,0.02276076],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002246078,"threshold_uncertainty_score":0.007513881,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0347343070403783,"score_gpt":0.3034874655204012,"score_spread":0.268753158480023,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}