{"id":"W2757884995","doi":"10.1021/acs.jpcb.7b07271","title":"Thermodynamic Investigation of the Effect of Interface Curvature on the Solid–Liquid Equilibrium and Eutectic Point of Binary Mixtures","year":2017,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"nanoparticles nucleation surface interactions","field":"Earth and Planetary Sciences","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Curvature; Eutectic system; Thermodynamics; Phase diagram; Materials science; Freezing point; Freezing-point depression; Chemistry; Phase (matter); Microstructure; Organic chemistry; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002380301,0.0002089679,0.0002853745,0.0005219225,0.0002371957,0.0003704987,0.0002447419,0.0001844673,0.0005056874],"category_scores_gemma":[0.0006680609,0.0001551972,0.0001761885,0.0003548706,0.0003866277,0.0004523118,0.000361843,0.0003524348,0.00009768493],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003605364,"about_ca_system_score_gemma":0.0002194558,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001069114,"about_ca_topic_score_gemma":0.0008451032,"domain_scores_codex":[0.9998293,0.00002760697,0.00001080467,0.00003341571,0.00007580026,0.00002301702],"domain_scores_gemma":[0.9997776,0.00009055161,0.00004707811,0.00001410549,0.00005167147,0.00001890456],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000221789,0.00004496052,0.003155451,0.0001084471,0.00002181389,0.0001346137,0.00009576386,0.007485367,0.982002,0.00219965,0.00004693121,0.004483192],"study_design_scores_gemma":[0.000007513274,0.000111434,0.005995179,0.000005604377,0.00001655563,0.00006761128,0.00004243909,0.08061101,0.9121933,0.0005027549,0.0004328622,0.00001375511],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944118,0.0004482051,0.004043344,0.00002308118,0.000003685077,0.00001013991,0.00006099609,0.00003220433,0.0009665819],"genre_scores_gemma":[0.9986494,0.0001406884,0.001005274,0.000004669078,0.000002125668,0.000006674906,0.00004062135,0.000007347594,0.0001431585],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001069114,"threshold_uncertainty_score":0.002615869,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009301882226775979,"score_gpt":0.2491334015792971,"score_spread":0.2398315193525211,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}