{"id":"W2758404224","doi":"10.1021/acs.orglett.7b02788","title":"An Intermolecular Azidoheteroarylation of Simple Alkenes via Free-Radical Multicomponent Cascade Reactions","year":2017,"lang":"en","type":"article","venue":"Organic Letters","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":91,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Nanjing University; University of Science and Technology of China; National Natural Science Foundation of China; Ryerson University","keywords":"Chemistry; Intermolecular force; Cascade; Combinatorial chemistry; Derivatization; Computational chemistry; Organic chemistry; Molecule","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007708026,0.0001876094,0.000233461,0.00004840162,0.000270669,0.00006991958,0.0008027278,0.0001612806,0.0009998516],"category_scores_gemma":[0.0004270815,0.0001893051,0.0001354371,0.00004350908,0.0003339907,0.0002922971,0.0001299078,0.000354465,0.00003582968],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001736095,"about_ca_system_score_gemma":0.00002381224,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007235579,"about_ca_topic_score_gemma":0.00003190841,"domain_scores_codex":[0.9986414,0.00002485824,0.000383762,0.0003624962,0.000312357,0.00027516],"domain_scores_gemma":[0.9977669,0.0000904197,0.0002933823,0.001586366,0.0000336498,0.000229243],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002029042,0.000164603,0.0005685285,0.00003506611,0.00005590457,0.00001952002,0.00007189654,0.00001040286,0.9975913,0.00002015742,0.0006835156,0.0007588508],"study_design_scores_gemma":[0.0006036921,0.00001558969,0.002682893,0.00003532239,0.00005267034,0.00003590362,0.0000184345,0.002039818,0.9922787,0.0002456373,0.001790893,0.0002004362],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.992739,0.000009544203,0.004099639,0.00245147,0.0001129949,0.0000877908,0.00002604995,0.0000961159,0.000377419],"genre_scores_gemma":[0.9986734,0.000004970449,0.0006559201,0.0003165363,0.0001927912,0.00001751231,0.00007482281,0.00004620813,0.00001780471],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005934458,"threshold_uncertainty_score":0.9999134,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.011601482059393,"score_gpt":0.259486867912042,"score_spread":0.247885385852649,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}