{"id":"W2758950617","doi":"10.1055/s-0036-1589105","title":"One-Pot Michael Addition/Radical Cyclization Reaction of N-Acryloyl Indoles","year":2017,"lang":"en","type":"article","venue":"Synlett","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Michael reaction; Radical cyclization; Addition reaction; Free-radical reaction; Acryloyl chloride; Organic chemistry; Radical; Catalysis; Acrylate","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002498355,0.0001344989,0.0002158819,0.00007642062,0.000273531,0.00005444597,0.0002684437,0.0001911335,0.002787619],"category_scores_gemma":[0.001271399,0.0001585207,0.00009571904,0.00007385765,0.0002339682,0.0002701822,0.00008350459,0.0001638666,0.00008129147],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009208528,"about_ca_system_score_gemma":0.00007918945,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001024284,"about_ca_topic_score_gemma":0.00003062282,"domain_scores_codex":[0.9987428,0.00003087124,0.0003725909,0.0002905428,0.0003978135,0.0001653724],"domain_scores_gemma":[0.9983807,0.0001390555,0.0004714325,0.0007664331,0.00016088,0.00008154833],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009488681,0.0002122548,0.005497154,0.0002760826,0.00008863789,0.000003718078,0.0001241288,0.00002376158,0.9660953,0.005951131,0.00621116,0.01542173],"study_design_scores_gemma":[0.002053087,0.00004101037,0.08423363,0.000434487,0.0001840022,0.0000547822,0.0001766221,0.0009785994,0.81563,0.00765861,0.08794751,0.0006076695],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8425396,0.0001491652,0.04780545,0.002670239,0.001310925,0.0002815394,0.0004914043,0.0003581621,0.1043935],"genre_scores_gemma":[0.991241,0.00004644728,0.003826746,0.0001273329,0.0007812856,0.00003248121,0.0007806532,0.0000423389,0.003121714],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1504654,"threshold_uncertainty_score":0.9981239,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03551202030588171,"score_gpt":0.303970434876941,"score_spread":0.2684584145710593,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}