{"id":"W2759078571","doi":"10.1039/c7dt03175k","title":"Synthesis and oxidation of phosphine cations","year":2017,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Einstein Stiftung Berlin; Alexander von Humboldt-Stiftung","keywords":"Carbene; Dication; Phosphine; Chemistry; Cationic polymerization; Oxazoline; Medicinal chemistry; Alkyl; Polymer chemistry; Organic chemistry; Ion; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008518023,0.0002227085,0.0001459594,0.0001016503,0.0001989667,0.0001830548,0.000269958,0.0002548278,0.002590298],"category_scores_gemma":[0.000169633,0.0001098035,0.00009776899,0.0001408525,0.000125805,0.0001928361,0.0002529428,0.0003267683,0.0005424439],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001929159,"about_ca_system_score_gemma":0.0001781901,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003112728,"about_ca_topic_score_gemma":0.000462938,"domain_scores_codex":[0.9999145,0.000007231842,0.000009836111,0.00002530186,0.00002428911,0.00001870959],"domain_scores_gemma":[0.9999444,0.000006439348,0.00001441461,0.000009059484,0.00001483721,0.00001085019],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007303955,0.00001017893,0.00006060142,0.0001430149,0.000003850509,0.00007216865,0.00002689464,0.0001340967,0.9945495,0.0006486717,0.0001804909,0.004097683],"study_design_scores_gemma":[0.00001238221,0.00007262577,0.0001875005,0.000002898467,0.000003454096,0.0001315286,0.000007080818,0.0001886628,0.9932185,0.00005693513,0.0061154,0.00000309668],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.952116,0.003874215,0.02291993,0.0002355804,0.0001410806,0.0001908896,0.000942597,0.0005007708,0.01907893],"genre_scores_gemma":[0.9793568,0.001463977,0.01116861,0.00007982808,0.0000190396,0.00007794199,0.0004550439,0.00004321418,0.007335514],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002590298,"threshold_uncertainty_score":0.008665383,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01389514308620798,"score_gpt":0.2506874417779991,"score_spread":0.2367922986917911,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}