{"id":"W2760398998","doi":"10.1021/jacs.7b09025","title":"A <i>N</i>-Heterocyclic Carbene-Stabilized Coinage Metal-Chalcogenide Framework with Tunable Optical Properties","year":2017,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":78,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; University of Alberta","keywords":"Chemistry; Chalcogen; Chalcogenide; Phosphorescence; Carbene; Metal; Ligand (biochemistry); Photochemistry; Metal ions in aqueous solution; Luminescence; Reactivity (psychology); Inorganic chemistry; Crystallography; Fluorescence; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002469354,0.000288759,0.0008512581,0.00001319288,0.0004228597,0.0001995742,0.001376354,0.00009358172,0.0006545646],"category_scores_gemma":[0.0004881563,0.0001579425,0.001244122,0.0001424339,0.001398001,0.0001810461,0.0004551543,0.0007041036,0.000005111329],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001777381,"about_ca_system_score_gemma":0.00008313503,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005737196,"about_ca_topic_score_gemma":0.000002432151,"domain_scores_codex":[0.9980511,0.00002885042,0.0005187531,0.0002879122,0.00069511,0.0004182827],"domain_scores_gemma":[0.9969229,0.0001670172,0.001380712,0.001169077,0.0001510794,0.0002092046],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001799614,0.0001685937,0.001585401,0.00004973362,0.0007602943,0.00000812626,0.0002503029,0.000008125322,0.9942527,0.00002726992,0.0001282522,0.002581266],"study_design_scores_gemma":[0.000538316,0.00004799197,0.00072017,0.0001568755,0.0006056889,0.0001487735,0.0008625754,0.00009295888,0.9915359,0.0003462372,0.004658591,0.0002859303],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949806,0.0002833203,0.00009604636,0.002202006,0.00004743142,0.00005290142,0.000007523776,0.00002138328,0.002308774],"genre_scores_gemma":[0.9943353,0.00009719976,0.004367422,0.0002616788,0.000330758,0.0000091319,5.048248e-7,0.00004491927,0.0005530753],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004530339,"threshold_uncertainty_score":0.7167024,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01843749431954851,"score_gpt":0.2375716728279211,"score_spread":0.2191341785083726,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}