{"id":"W2761111935","doi":"10.1021/acs.orglett.7b02488","title":"Iron-Catalyzed Carbene Insertion Reactions of α-Diazoesters into Si–H Bonds","year":2017,"lang":"en","type":"article","venue":"Organic Letters","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":82,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Université Laval","keywords":"Chemistry; Carbene; Catalysis; Insertion reaction; Diazo; Salt (chemistry); Medicinal chemistry; Combinatorial chemistry; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001711774,0.0004979275,0.0002328313,0.0002136277,0.0001289564,0.0001631581,0.0003806287,0.000306173,0.000962937],"category_scores_gemma":[0.0001261193,0.0001692346,0.000252237,0.0001102933,0.000253641,0.0002934307,0.000288879,0.000521643,0.0003655166],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003567305,"about_ca_system_score_gemma":0.0001775664,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006256099,"about_ca_topic_score_gemma":0.001413022,"domain_scores_codex":[0.9998858,0.00001242982,0.000006932094,0.00002409356,0.00002543325,0.00004538574],"domain_scores_gemma":[0.9999539,0.0000110821,0.000009866647,0.000005677741,0.000007941399,0.00001154245],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006440401,0.00003548785,0.0001227325,0.0001290493,0.00001735806,0.0002802231,0.00006509839,0.0003045819,0.9942912,0.0007706886,0.0001441326,0.003775125],"study_design_scores_gemma":[0.00001554431,0.0001228615,0.0002716544,0.000004165473,0.000007901694,0.0001108087,0.000009556583,0.0003993936,0.9972008,0.0000439781,0.001807054,0.000006193091],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9713541,0.00268373,0.01265207,0.0001509973,0.00007997137,0.0001221551,0.0002123452,0.0001608275,0.0125837],"genre_scores_gemma":[0.9913563,0.001213692,0.003874398,0.00003656618,0.00001227673,0.00002438266,0.0001217253,0.00001526598,0.003345436],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000962937,"threshold_uncertainty_score":0.003221393,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0105054377729668,"score_gpt":0.2315349884809678,"score_spread":0.221029550708001,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}