{"id":"W2761834037","doi":"10.1002/chem.201702943","title":"Radical Behavior of CO<sub>2</sub> versus its Deoxygenation Promoted by Vanadium Aryloxide Complexes: How the Geometry of Intermediate CO<sub>2</sub>‐Adducts Determines the Reactivity.","year":2017,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Reactivity (psychology); Carbon monoxide; Chemistry; Deoxygenation; Vanadium; Ligand (biochemistry); Adduct; Inorganic chemistry; Photochemistry; Medicinal chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001151915,0.0002399981,0.0001605694,0.00009841103,0.0001257384,0.0002729823,0.0002891283,0.0002922127,0.002958778],"category_scores_gemma":[0.000268659,0.00008100587,0.00009121097,0.000110439,0.0002390018,0.0003107856,0.0001604185,0.0003368956,0.0003809384],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001686074,"about_ca_system_score_gemma":0.00009705199,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004842138,"about_ca_topic_score_gemma":0.0008149174,"domain_scores_codex":[0.9999341,0.000007321895,0.000002025651,0.00001828988,0.00001342001,0.00002477163],"domain_scores_gemma":[0.9999161,0.00002262116,0.00002094241,0.00000912529,0.00001967637,0.00001150029],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003740727,0.00002800342,0.0004786555,0.0001580085,0.00001765679,0.00009665997,0.00009938989,0.0003129152,0.9944547,0.0005311755,0.0001480669,0.003300828],"study_design_scores_gemma":[0.000008369699,0.000255315,0.000990618,0.00000535242,0.00001078798,0.00008082017,0.00004441488,0.001190727,0.996159,0.00009617231,0.001149669,0.000008817682],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956496,0.001013662,0.0009223268,0.00005551716,0.00003091702,0.00001386496,0.0001295657,0.00003666158,0.002147953],"genre_scores_gemma":[0.9986759,0.0002663216,0.0001812441,0.000009497145,0.000003374567,0.000004171181,0.00006419092,0.000007852136,0.0007873489],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002958778,"threshold_uncertainty_score":0.009898067,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02602943496209626,"score_gpt":0.259471124369082,"score_spread":0.2334416894069857,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}