{"id":"W2762812029","doi":"10.1016/j.gca.2017.10.002","title":"Kinetic stable Cr isotopic fractionation between aqueous Cr(III)-Cl-H2O complexes at 25 °C: Implications for Cr(III) mobility and isotopic variations in modern and ancient natural systems","year":2017,"lang":"en","type":"article","venue":"Geochimica et Cosmochimica Acta","topic":"Chromium effects and bioremediation","field":"Environmental Science","cited_by":29,"is_retracted":false,"has_abstract":false,"ca_institutions":"Memorial University of Newfoundland","funders":"Deutsche Forschungsgemeinschaft","keywords":"Fractionation; Chemistry; Dissolution; Isotope fractionation; Ligand (biochemistry); Aqueous solution; Adsorption; Isotopologue; Elution; Redox; Equilibrium fractionation; Isotope; Inorganic chemistry; Physical chemistry; Chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003063879,0.0001911984,0.0001390782,0.0002220593,0.0002334936,0.0005423157,0.0004575638,0.0003058868,0.0008472811],"category_scores_gemma":[0.0004701277,0.0001687432,0.0001523437,0.0002116622,0.0004009513,0.0003530343,0.0001525244,0.0002882119,0.0001633016],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007988079,"about_ca_system_score_gemma":0.0003895994,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.008877496,"about_ca_topic_score_gemma":0.00808259,"domain_scores_codex":[0.9998448,0.00001406648,0.00001089033,0.00004722959,0.00004005801,0.000042974],"domain_scores_gemma":[0.9998665,0.00003225292,0.00002175277,0.00001354892,0.00005132999,0.00001465356],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007890394,0.00002598232,0.002807521,0.00003742026,0.00001719572,0.00003491759,0.0001043331,0.0002785221,0.9926382,0.0002715235,0.00009212993,0.00290322],"study_design_scores_gemma":[0.00003334425,0.000146209,0.01199319,0.000004109884,0.00001959875,0.00004885449,0.0001166373,0.001667967,0.9847116,0.0001373342,0.001106971,0.00001407633],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960224,0.0004084255,0.00190048,0.00005725705,0.00001836248,0.00001716742,0.0003184767,0.00002673134,0.001230739],"genre_scores_gemma":[0.998887,0.00008630189,0.0003623331,0.00001158737,0.000002791856,0.000006460418,0.0001176302,0.000006965679,0.0005189486],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008877496,"threshold_uncertainty_score":0.01765162,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01844922872251507,"score_gpt":0.2694022255367038,"score_spread":0.2509529968141887,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}