{"id":"W2763378440","doi":"10.1021/acs.macromol.7b01765","title":"Rapid Synthesis of Functionalized High-Generation Polyester Dendrimers via Strain-Promoted Alkyne–Azide Cycloaddition","year":2017,"lang":"en","type":"article","venue":"Macromolecules","topic":"Dendrimers and Hyperbranched Polymers","field":"Materials Science","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Dendrimer; Cycloaddition; Azide; Polyester; Alkyne; Chemistry; Convergent synthesis; Dispersity; Combinatorial chemistry; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000299811,0.0002438022,0.0003548019,0.0001081566,0.000506178,0.0002023027,0.0004307079,0.0001300822,0.005091568],"category_scores_gemma":[0.0001332238,0.0002309251,0.0001503298,0.00005872325,0.0003980055,0.0003716642,0.00008965775,0.00008492556,0.0002365332],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004218573,"about_ca_system_score_gemma":0.00005928461,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006415449,"about_ca_topic_score_gemma":0.0001049563,"domain_scores_codex":[0.9982691,0.0001387043,0.0003996783,0.0004385342,0.000407166,0.0003467876],"domain_scores_gemma":[0.9985821,0.00006313948,0.0004335715,0.0007038928,0.0001006294,0.000116681],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006710264,0.00007146771,0.00005971085,0.00002212424,0.00004573696,0.00001891217,0.00009655163,0.00001132702,0.9730651,0.0005239653,0.0005463141,0.02547164],"study_design_scores_gemma":[0.000580908,0.00007198315,0.004813978,0.00004929712,0.0001042633,0.000023965,0.00003936736,0.0001309321,0.9921712,0.0002731618,0.001469976,0.0002709632],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9908867,0.0004182534,0.002432929,0.0005012772,0.001175471,0.0002232051,0.0005053578,0.00007689606,0.003779937],"genre_scores_gemma":[0.9968626,0.00003284145,0.002120203,0.0001240931,0.0002506005,0.00004416132,0.0001347349,0.00003704883,0.000393734],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02520068,"threshold_uncertainty_score":0.9958179,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01999829914362886,"score_gpt":0.2451717859443991,"score_spread":0.2251734868007703,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}