{"id":"W2763391983","doi":"10.1021/acs.joc.7b02172","title":"Synthesis of a Pentasaccharide Fragment Related to the Inner Core Region of Rhizobial and Agrobacterial Lipopolysaccharides","year":2017,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"National Institute of Allergy and Infectious Diseases; Austrian Science Fund","keywords":"Chemistry; Disaccharide; Tetrasaccharide; Stereochemistry; Oxazoline; Moiety; Glycosylation; Mannose; Total synthesis; Yield (engineering); Glycosyl donor; Monosaccharide; Convergent synthesis; Polysaccharide; Organic chemistry; Glycoside; Biochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000666667,0.0002318252,0.0005102817,0.00001990208,0.0002689016,0.00005507695,0.001232479,0.0001897715,0.001465153],"category_scores_gemma":[0.001374491,0.0001435703,0.0001903947,0.00008071085,0.0003447029,0.000104457,0.0003315537,0.0003858855,0.000002198993],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007467638,"about_ca_system_score_gemma":0.0001358139,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004942715,"about_ca_topic_score_gemma":0.000005013084,"domain_scores_codex":[0.998359,0.00002747038,0.0008369111,0.0001695701,0.0003937763,0.0002132537],"domain_scores_gemma":[0.9966128,0.0003996058,0.001659769,0.0009907108,0.000206881,0.0001301585],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005055114,0.00007431852,0.0005655637,0.0002077599,0.0002301427,0.00001739299,0.0007537752,0.000005707335,0.9963157,0.000003414129,0.0005430759,0.0007776734],"study_design_scores_gemma":[0.0004583781,0.00001896177,0.0003844348,0.0004754736,0.0003428917,0.0004652553,0.0009606204,0.00001101981,0.9964155,0.0001170227,0.0002019958,0.0001484375],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969146,0.0001946164,0.000006728588,0.001705454,0.0001268567,0.00005195021,0.00002831549,0.000007403012,0.0009640254],"genre_scores_gemma":[0.9988402,0.0003474697,0.00003548083,0.00002158815,0.0003035776,0.000002514667,0.000001359708,0.00002753496,0.0004202705],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001925553,"threshold_uncertainty_score":0.9994476,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.016193616819449,"score_gpt":0.2331673233795017,"score_spread":0.2169737065600527,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}