{"id":"W2763391983","doi":"10.1021/acs.joc.7b02172","title":"Synthesis of a Pentasaccharide Fragment Related to the Inner Core Region of Rhizobial and Agrobacterial Lipopolysaccharides","year":2017,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"National Institute of Allergy and Infectious Diseases; Austrian Science Fund","keywords":"Chemistry; Disaccharide; Tetrasaccharide; Stereochemistry; Oxazoline; Moiety; Glycosylation; Mannose; Total synthesis; Yield (engineering); Glycosyl donor; Monosaccharide; Convergent synthesis; Polysaccharide; Organic chemistry; Glycoside; Biochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009694727,0.000408361,0.0003197775,0.0001817987,0.0001387224,0.000197881,0.0002433351,0.0002357754,0.001106004],"category_scores_gemma":[0.0001221111,0.0001565456,0.0002802954,0.0002734676,0.0001059801,0.0001771335,0.0003128519,0.0004067004,0.0005494443],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002754224,"about_ca_system_score_gemma":0.000341849,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006293248,"about_ca_topic_score_gemma":0.0007610306,"domain_scores_codex":[0.9999119,0.00001134484,0.000008683022,0.00002112073,0.00002091478,0.0000260953],"domain_scores_gemma":[0.9999169,0.000006555028,0.00001827345,0.00001487229,0.00001222805,0.00003116561],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007145709,0.00002141542,0.00006554394,0.0000359806,0.000006388549,0.00009405917,0.00002072201,0.0001843504,0.9966648,0.0002393673,0.00002638867,0.002569486],"study_design_scores_gemma":[0.0000203512,0.0002971264,0.001080734,0.0000054557,0.00002363357,0.0002703654,0.00001493532,0.0005178777,0.9928912,0.00007333019,0.004793374,0.00001148336],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9747522,0.0007774855,0.01987877,0.00007433564,0.00005253335,0.0001660144,0.0006926121,0.0001288028,0.003477293],"genre_scores_gemma":[0.9650012,0.0008641379,0.02801116,0.00005305595,0.00001056349,0.0001089904,0.001512905,0.00004952504,0.004388429],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001106004,"threshold_uncertainty_score":0.003699899,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.016193616819449,"score_gpt":0.2331673233795017,"score_spread":0.2169737065600527,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}