{"id":"W2763833008","doi":"10.1021/jacs.7b09251","title":"Ultrahigh Mass Activity for Carbon Dioxide Reduction Enabled by Gold–Iron Core–Shell Nanoparticles","year":2017,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":218,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada)","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; University of Saskatchewan; Natural Science Foundation of Heilongjiang Province; National Research Council Canada; National Natural Science Foundation of China; Office of Science","keywords":"Overpotential; Chemistry; Nanoparticle; Alloy; Catalysis; Leaching (pedology); Chemical engineering; Electrochemistry; Electrochemical reduction of carbon dioxide; Carbon dioxide; Selectivity; Nanotechnology; Physical chemistry; Electrode; Materials science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001325128,0.0003227164,0.0001318318,0.0001885576,0.000143085,0.0002496187,0.0002812122,0.0003097771,0.001770012],"category_scores_gemma":[0.0001219455,0.0001767613,0.0001154263,0.00009127118,0.0002064168,0.0002085118,0.0001561685,0.0002600349,0.0003737247],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004065601,"about_ca_system_score_gemma":0.0001146382,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001051516,"about_ca_topic_score_gemma":0.001773295,"domain_scores_codex":[0.9999158,0.00000566474,0.000004440856,0.00002692042,0.0000316876,0.00001541376],"domain_scores_gemma":[0.9999558,0.00001423673,0.000005831902,0.000005542907,0.00001065927,0.000007972724],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002567242,0.00000752358,0.00004543197,0.00001537604,0.000001499862,0.00002416388,0.000009088074,0.00009327327,0.99826,0.0001233804,0.0001193977,0.00127525],"study_design_scores_gemma":[0.000002415998,0.00002317955,0.0002642246,7.422233e-7,0.000001519843,0.00001607364,0.000003516192,0.001452697,0.9977617,0.00001359456,0.000458598,0.000001660124],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9837117,0.0004251735,0.00831479,0.0001648551,0.0000471078,0.00002317917,0.0002199841,0.0004931549,0.006600092],"genre_scores_gemma":[0.9901047,0.0001820043,0.005711055,0.00003515487,0.000007075509,0.00002187239,0.000179028,0.00003698749,0.003722044],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001770012,"threshold_uncertainty_score":0.005921304,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01322986137166129,"score_gpt":0.2619579642509584,"score_spread":0.2487281028792971,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}