{"id":"W2765660373","doi":"10.1002/anie.201710241","title":"A Nickel‐Catalyzed Carbonyl‐Heck Reaction","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":78,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Ontario Ministry of Economic Development and Innovation","keywords":"Catalysis; Chemistry; Heck reaction; Aldehyde; Olefin fiber; Ligand (biochemistry); Reactivity (psychology); Nickel; Coupling reaction; Combinatorial chemistry; Ketone; Intermolecular force; Amine gas treating; Organic synthesis; Molecule; Organic chemistry; Palladium","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002159416,0.0005411261,0.0002085752,0.0003331126,0.0005552983,0.000341776,0.0006576166,0.0003340387,0.006128657],"category_scores_gemma":[0.000166881,0.0001880072,0.0002858925,0.0002630634,0.0002305282,0.0005340267,0.0005813102,0.0006508534,0.002269208],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005574315,"about_ca_system_score_gemma":0.0006149272,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008012258,"about_ca_topic_score_gemma":0.001535491,"domain_scores_codex":[0.9997477,0.0000219617,0.00002177887,0.00005699824,0.00007562448,0.00007582922],"domain_scores_gemma":[0.9999417,0.000006483648,0.000008531393,0.00001379075,0.00001332198,0.0000160884],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002503807,0.0005066568,0.001072348,0.001149387,0.0001198873,0.00196312,0.0003902698,0.001211233,0.9026955,0.02125146,0.008329346,0.06106032],"study_design_scores_gemma":[0.00003334065,0.0003975581,0.0008694634,0.00002679485,0.00005172734,0.001005142,0.00005840884,0.001086124,0.9546235,0.0005308964,0.04128998,0.00002700302],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7073596,0.00519731,0.0603038,0.001175663,0.001193567,0.0005878985,0.001579921,0.001646891,0.2209553],"genre_scores_gemma":[0.9730069,0.001741552,0.008152851,0.00009826096,0.00005929328,0.00007074395,0.0004367064,0.00003708721,0.0163967],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006128657,"threshold_uncertainty_score":0.02050245,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02187104509942413,"score_gpt":0.2990541934416978,"score_spread":0.2771831483422736,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}