{"id":"W2765759113","doi":"10.1016/j.ica.2017.10.027","title":"Bio-inspired oxidation chemistry of a Cu(II)-fluoride cryptate with C3-symmetry","year":2017,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":false,"ca_institutions":"Concordia University","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Fluoride; Copper; Protonation; Chloride; Moiety; Electron paramagnetic resonance; Cryptand; Crystallography; Inorganic chemistry; Coordination sphere; Ligand (biochemistry); Ion; Ultraviolet visible spectroscopy; Crystal structure; Photochemistry; Medicinal chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002379984,0.0004066439,0.0005128114,0.00007694086,0.0005398802,0.0001386105,0.001486266,0.000311758,0.002514814],"category_scores_gemma":[0.0007256354,0.0003762747,0.0001508283,0.0001806799,0.0002276874,0.0004558241,0.000490759,0.0003894814,0.00006819407],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000119842,"about_ca_system_score_gemma":0.0002158731,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006116014,"about_ca_topic_score_gemma":0.00001669409,"domain_scores_codex":[0.9975885,0.00002066643,0.0006480877,0.000682597,0.0006209643,0.0004391484],"domain_scores_gemma":[0.9959076,0.00007765148,0.001154013,0.002377485,0.0002565197,0.0002267384],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008357748,0.0001860497,0.0008276931,0.0001965854,0.0001569478,0.000004902634,0.0001830123,3.45082e-7,0.9975049,0.0002283982,0.0003505301,0.0002769905],"study_design_scores_gemma":[0.001377319,0.00003001655,0.001550739,0.0001228287,0.0001274843,0.00003899702,0.00008975375,0.0001071747,0.9936233,0.0003826477,0.002115672,0.0004340907],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.983441,0.00001921073,0.00008066317,0.0008948936,0.0001154983,0.0001360006,0.0001076501,0.0001855432,0.01501957],"genre_scores_gemma":[0.9946703,0.00004583459,0.002970888,0.00006467081,0.0002207615,0.00002389467,0.0002127108,0.00009895174,0.001692008],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01332756,"threshold_uncertainty_score":0.9998689,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01463075091970318,"score_gpt":0.2361723280899478,"score_spread":0.2215415771702446,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}