{"id":"W2765974216","doi":"10.1021/acsomega.7b01352","title":"The <i>trans</i>-Bis(<i>p</i>-thioetherphenylacetynyl)bis(phosphine)platinum(II) Ligands: A Step towards Predictability and Crystal Design","year":2017,"lang":"en","type":"article","venue":"ACS Omega","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Crystallization; Crystallography; Molecule; Phosphine; Cubane; Steric effects; Solvent; Halide; Crystal structure; Inorganic chemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts"],"consensus_categories":[],"category_scores_codex":[0.001130932,0.0004040022,0.0004379605,0.00002015397,0.00252178,0.0005947722,0.001240318,0.000382171,0.0002459992],"category_scores_gemma":[0.001076491,0.0002941636,0.0001607472,0.0001024092,0.0006286027,0.0002840179,0.0003861105,0.000620792,0.00001104638],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005701881,"about_ca_system_score_gemma":0.0001968613,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000145622,"about_ca_topic_score_gemma":0.0000739167,"domain_scores_codex":[0.9976478,0.00004790172,0.0005635386,0.0006919227,0.0004779132,0.0005709209],"domain_scores_gemma":[0.9961972,0.0006921816,0.0003804209,0.002359379,0.0001277277,0.0002431424],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0003404956,0.0006752496,0.0049213,0.000367946,0.000527907,0.00001289739,0.002438723,0.00002253748,0.8730774,0.005546765,0.01843254,0.09363627],"study_design_scores_gemma":[0.002332244,0.0001611241,0.006149675,0.0002986295,0.0004269741,0.00006119096,0.0009682734,0.001277626,0.4787344,0.006080994,0.5022102,0.001298612],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9511214,0.002894578,0.01107046,0.007644875,0.0002466485,0.0006776726,0.0001921513,0.0003054276,0.0258468],"genre_scores_gemma":[0.991648,0.0009636527,0.002630263,0.0001605552,0.0003161259,0.0002166874,0.0000113081,0.00006928373,0.003984085],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4837777,"threshold_uncertainty_score":0.9999511,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02122285584307253,"score_gpt":0.2522302999197258,"score_spread":0.2310074440766533,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}