{"id":"W2766321472","doi":"10.1021/acs.organomet.7b00614","title":"Activation of Dioxygen by Dimethylplatinum(II) Complexes","year":2017,"lang":"en","type":"article","venue":"Organometallics","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Reactivity (psychology); Medicinal chemistry; Solvent; Oxygen; Stereochemistry; Oxygen atom; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001214675,0.0002972865,0.0001744753,0.0001057695,0.0001322967,0.000295096,0.0005624228,0.0002823944,0.001687833],"category_scores_gemma":[0.0001578912,0.000199913,0.0001085454,0.0001109114,0.000152995,0.0002248336,0.0003846659,0.0003239932,0.0003414788],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004522369,"about_ca_system_score_gemma":0.00012528,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003898176,"about_ca_topic_score_gemma":0.0008828536,"domain_scores_codex":[0.9998441,0.00002187577,0.00001106576,0.00004103746,0.0000384791,0.00004345317],"domain_scores_gemma":[0.9999479,0.00001042081,0.00001586784,0.000006738131,0.000005369546,0.00001367459],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001001672,0.00001571722,0.0001127711,0.00007620255,0.000003783856,0.00002947799,0.00003370585,0.0001416299,0.9974142,0.0003942854,0.000102861,0.001575208],"study_design_scores_gemma":[0.00001140056,0.00005350264,0.0001818576,0.000001899663,0.00000274218,0.00002625609,0.000006093872,0.0003672681,0.9977192,0.00003284244,0.00159419,0.000002701858],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9897072,0.001084021,0.00421818,0.0001528191,0.00005068223,0.00003940411,0.0001712406,0.0001257334,0.004450676],"genre_scores_gemma":[0.9944655,0.0004411745,0.00217092,0.00004379327,0.000008388461,0.0000193,0.0001437515,0.00001848288,0.00268855],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001687833,"threshold_uncertainty_score":0.005646348,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02295071008836715,"score_gpt":0.2609942812787539,"score_spread":0.2380435711903867,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}