{"id":"W2766799023","doi":"10.1021/acs.joc.7b01880","title":"Boronic Acids as Phase-Transfer Reagents for Fischer Glycosidations in Low-Polarity Solvents","year":2017,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Research, Innovation and Science; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Chemistry; Boronic acid; Phenylboronic acid; Reagent; Diol; Organic chemistry; Substrate (aquarium); Combinatorial chemistry; Organic synthesis; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001996109,0.0004722143,0.0002647329,0.0001831635,0.0002546442,0.0003068053,0.0003616539,0.0002256705,0.002155411],"category_scores_gemma":[0.0002556669,0.0002784626,0.000205814,0.0002262671,0.0001526287,0.0003726455,0.0002981199,0.0008333637,0.001333219],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003580142,"about_ca_system_score_gemma":0.0003578659,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006197105,"about_ca_topic_score_gemma":0.001161857,"domain_scores_codex":[0.9998993,0.00001668617,0.000004966444,0.00001722502,0.00003736927,0.000024405],"domain_scores_gemma":[0.9999497,0.00001609712,0.00001292516,0.000006729762,0.000008176116,0.000006427981],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00026942,0.00008706563,0.000233083,0.0006708712,0.00002305811,0.0001179461,0.0000744381,0.01055271,0.9531454,0.01046366,0.0009178445,0.02344453],"study_design_scores_gemma":[0.00006571055,0.0002418441,0.0001535123,0.00003032483,0.00001663541,0.00007823768,0.00002145794,0.007594466,0.9774854,0.001983973,0.01230752,0.00002081099],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7616572,0.006989135,0.2058464,0.0003207336,0.0001744546,0.0005052316,0.001099348,0.001406409,0.02200123],"genre_scores_gemma":[0.9038575,0.006306127,0.08287266,0.0001062681,0.00002330449,0.0004196868,0.0007096287,0.0002179981,0.005486845],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002155411,"threshold_uncertainty_score":0.007210612,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02131389609810934,"score_gpt":0.2913617757135101,"score_spread":0.2700478796154007,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}