{"id":"W2766911795","doi":"10.1039/c7ra09165f","title":"Development of a metal-free amine oxidation method utilizing DEAD chemistry","year":2017,"lang":"en","type":"article","venue":"RSC Advances","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Winnipeg; University of Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Dehydrogenation; Oxidizing agent; Chemistry; Amine gas treating; Metal; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001171126,0.0001189523,0.0002065204,0.00001001806,0.0002484807,0.00002537325,0.0003907184,0.00007678662,0.0005372631],"category_scores_gemma":[0.0004667006,0.000101017,0.0000758854,0.00002572474,0.00006781401,0.0001916013,0.0001382051,0.00009302299,0.000006117987],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004378198,"about_ca_system_score_gemma":0.00003344722,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009607767,"about_ca_topic_score_gemma":0.0000186698,"domain_scores_codex":[0.9991839,0.000003794847,0.000266755,0.0002157195,0.0001791592,0.0001506524],"domain_scores_gemma":[0.9989091,0.00009825098,0.0003253332,0.0005643758,0.00004774886,0.00005515411],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000007909453,0.0000511882,0.0001904721,0.000143325,0.00003495903,6.614998e-7,0.00004293705,0.000001174838,0.8805004,0.00005323259,0.00001324236,0.1189605],"study_design_scores_gemma":[0.0001818784,9.195223e-7,0.0001823592,0.00007841879,0.00002609158,0.000003414088,0.0001636909,0.00003708053,0.9047158,0.0003750643,0.09412009,0.0001151452],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9134602,0.001070372,0.003705537,0.0001808409,0.00007039641,0.00004181661,0.00001596877,0.00006592245,0.08138895],"genre_scores_gemma":[0.8603224,0.0001217425,0.1377875,0.000004650901,0.0001148892,0.00002273698,0.00001947406,0.00001498991,0.001591654],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1340819,"threshold_uncertainty_score":0.5882655,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03349455924035329,"score_gpt":0.3187966852467818,"score_spread":0.2853021260064285,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}