{"id":"W2767402591","doi":"10.1021/acs.macromol.7b01933","title":"Poly(<i>p</i>-phenylenediethynylene phosphine)s and Related π-Conjugated Phosphine–Diyne Polymers: Synthesis, Characterization and Photophysical Properties","year":2017,"lang":"en","type":"article","venue":"Macromolecules","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Conjugated system; Phosphine; Polymer; Macromolecule; Polystyrene; Polymer chemistry; Chemistry; Fluorescence; Characterization (materials science); Triethylamine; Photochemistry; Organic chemistry; Materials science; Combinatorial chemistry; Catalysis; Nanotechnology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000160019,0.0002548686,0.0001181196,0.0002326555,0.00009754578,0.0002469923,0.0001287247,0.0002887449,0.000743082],"category_scores_gemma":[0.0002144869,0.0001871141,0.0001126879,0.0002345214,0.0001969605,0.0003942876,0.000103356,0.000305314,0.0003185063],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001822896,"about_ca_system_score_gemma":0.0001118647,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001374912,"about_ca_topic_score_gemma":0.0002245947,"domain_scores_codex":[0.999922,0.0000120573,0.000007205055,0.00002444035,0.0000215144,0.00001282921],"domain_scores_gemma":[0.9999062,0.00002550345,0.00003690452,0.000007664728,0.000009012422,0.00001458249],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005017385,0.00003607052,0.0002104742,0.00009695985,0.000003362224,0.00006389285,0.00002050768,0.000263071,0.99566,0.0003636376,0.0000358877,0.003195933],"study_design_scores_gemma":[0.000005196583,0.0002372137,0.001426996,0.000003122406,0.000004488116,0.0001454013,0.000007013176,0.0006446501,0.9952922,0.00006340643,0.00216553,0.000004771127],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9831346,0.003945496,0.009559635,0.0001135362,0.00001992344,0.00005892939,0.0002695591,0.00004605688,0.00285219],"genre_scores_gemma":[0.9834283,0.003002308,0.009748026,0.00004898678,0.00001495602,0.00005819377,0.0003569044,0.000016693,0.003325587],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000743082,"threshold_uncertainty_score":0.002485871,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01128238182982812,"score_gpt":0.2179894198554197,"score_spread":0.2067070380255916,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}