{"id":"W2767590229","doi":"10.1021/acs.jpcb.7b07992","title":"Nonideal Solute Chemical Potential Equation and the Validity of the Grouped Solute Approach for Intracellular Solution Thermodynamics","year":2017,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Advanced Thermodynamics and Statistical Mechanics","field":"Physics and Astronomy","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; University of Alberta; Canadian Institutes of Health Research; Alberta Innovates - Technology Futures","keywords":"Thermodynamics; Aqueous solution; Chemistry; Virial coefficient; Work (physics); Cryobiology; Osmosis; Virial theorem; Activity coefficient; Osmotic coefficient; Statistical physics; Physical chemistry; Physics; Cryopreservation; Membrane","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009099659,0.0004661699,0.000601934,0.001020733,0.000673563,0.0007164621,0.001610926,0.001190851,0.00160135],"category_scores_gemma":[0.002431071,0.0002352506,0.0009179963,0.0004232771,0.001801469,0.002436968,0.001669009,0.001113363,0.0004615757],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001031334,"about_ca_system_score_gemma":0.001088068,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001496125,"about_ca_topic_score_gemma":0.001285452,"domain_scores_codex":[0.9995928,0.00009933017,0.00002051538,0.00006515934,0.0001647886,0.0000573963],"domain_scores_gemma":[0.9993197,0.0002804452,0.0001067454,0.00009262595,0.0001413216,0.00005928615],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.00002066677,0.00003490695,0.0007549149,0.00007588587,0.00001749473,0.0002003141,0.0001292197,0.1172937,0.0132927,0.8598045,0.0007214965,0.007654103],"study_design_scores_gemma":[0.000009631215,0.00002858889,0.0003018865,0.0000147966,0.000007454026,0.00007548572,0.00002789413,0.5889021,0.003056371,0.4052145,0.002341886,0.00001937407],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":"theoretical_or_conceptual","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.09470554,0.001165861,0.890273,0.001267399,0.0002542595,0.00005824587,0.000130994,0.0001082281,0.01203646],"genre_scores_gemma":[0.8418308,0.001503379,0.1403819,0.0007490165,0.0002591995,0.0002678196,0.0001842712,0.0001790112,0.01464461],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.001610926,"threshold_uncertainty_score":0.007482946,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01574845299593915,"score_gpt":0.2480418651298218,"score_spread":0.2322934121338827,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}