{"id":"W2767690775","doi":"10.1088/1742-6596/950/4/042055","title":"Forcing Cesium into Higher Oxidation States Using Useful hard x-ray Induced Chemistry under High Pressure","year":2017,"lang":"en","type":"article","venue":"Journal of Physics Conference Series","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada)","funders":"","keywords":"Caesium; XANES; Fluoride; Chemistry; Oxidation state; Fluorine; Tetrafluoroborate; Inorganic chemistry; Decomposition; Absorption (acoustics); Spectroscopy; Absorption spectroscopy; X-ray absorption spectroscopy; Physical chemistry; Materials science; Organic chemistry; Catalysis; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002105981,0.0002719777,0.0001914541,0.0001338722,0.0002277543,0.0003661706,0.000313231,0.0002321443,0.001899434],"category_scores_gemma":[0.0003197778,0.000175274,0.000230652,0.000118485,0.000355315,0.0005211071,0.0004498576,0.0005763941,0.0003236586],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003093097,"about_ca_system_score_gemma":0.0002493492,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004322829,"about_ca_topic_score_gemma":0.0008850372,"domain_scores_codex":[0.9998472,0.00001525953,0.00001149561,0.00003865185,0.00006095317,0.00002657198],"domain_scores_gemma":[0.9998492,0.0000450345,0.00004711355,0.00002926418,0.00001863986,0.00001082904],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006197781,0.00001555587,0.0003264704,0.0002049244,0.000008659953,0.00009166246,0.000134612,0.0001999787,0.9946595,0.001143318,0.0001291856,0.003024123],"study_design_scores_gemma":[0.00001322247,0.00010758,0.0005653198,0.000004055933,0.000004407639,0.00009162995,0.00002444469,0.0003146488,0.9955735,0.0001255162,0.00317133,0.000004318881],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.982567,0.0008128964,0.01047315,0.000301671,0.00006451862,0.00006560342,0.0001677647,0.0001868917,0.005360486],"genre_scores_gemma":[0.9890785,0.0006037175,0.007365149,0.0000744143,0.00002674182,0.0000375114,0.0001275962,0.00009973168,0.002586685],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001899434,"threshold_uncertainty_score":0.006354213,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03201982994688666,"score_gpt":0.2552084984921111,"score_spread":0.2231886685452245,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}