{"id":"W2767725467","doi":"10.1002/chem.201705276","title":"C−F Bond Activation by Silylium Cation/Phosphine Frustrated Lewis Pairs: Mono‐Hydrodefluorination of PhCF<sub>3</sub>, PhCF<sub>2</sub>H and Ph<sub>2</sub>CF<sub>2</sub>","year":2017,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":76,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Phosphine; Chemistry; Aryl; Frustrated Lewis pair; Lewis acids and bases; Polymer chemistry; Base (topology); Phosphine oxide; Intermolecular force; Medicinal chemistry; Organic chemistry; Alkyl; Molecule; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.002840713,0.001381603,0.001160957,0.0002004807,0.001875469,0.0005492196,0.001690589,0.0009450236,0.0002568864],"category_scores_gemma":[0.001811767,0.001559833,0.0004312498,0.0006087643,0.001152913,0.001277491,0.0006759434,0.004258886,0.0001793461],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007303012,"about_ca_system_score_gemma":0.0006318731,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000102941,"about_ca_topic_score_gemma":0.000005783091,"domain_scores_codex":[0.9930304,0.0006712263,0.002239397,0.001549284,0.001007126,0.001502621],"domain_scores_gemma":[0.9924255,0.0005039249,0.003126252,0.001472373,0.001216631,0.001255336],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006125208,0.0009743631,0.002071209,0.0005626727,0.0006304794,0.0003058699,0.0005528642,0.0001780421,0.9403949,0.00000919364,0.03013202,0.02357586],"study_design_scores_gemma":[0.005906545,0.0002116936,0.002791618,0.0003390069,0.00059912,0.0009797643,0.0002647329,0.001806655,0.9818154,0.0001792247,0.00370487,0.001401353],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9918816,0.001105582,0.0002526413,0.001645834,0.00114247,0.0006103684,0.000329686,0.0002939875,0.002737813],"genre_scores_gemma":[0.9927016,0.003311895,0.00008008652,0.0003847078,0.002386086,0.00004592345,0.0005428939,0.0003311215,0.0002157008],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04142052,"threshold_uncertainty_score":0.9998934,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03766178601755402,"score_gpt":0.3142565990532207,"score_spread":0.2765948130356667,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}