{"id":"W2767811350","doi":"10.1002/ange.201710337","title":"1,1‐Hydroboration and a Borane Adduct of Diphenyldiazomethane: A Potential Prelude to FLP‐N<sub>2</sub> Chemistry","year":2017,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":82,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Borane; Hydroboration; Chemistry; Adduct; Steric effects; Carbene; Frustrated Lewis pair; Medicinal chemistry; Stereochemistry; Boranes; Lewis acids and bases; Organic chemistry; Catalysis; Boron","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001537818,0.0004022544,0.0005042605,0.00003588091,0.0002786834,0.0001702469,0.0006085868,0.0003908458,0.0008409226],"category_scores_gemma":[0.0004065543,0.0004311645,0.0001392491,0.0001075137,0.0002657125,0.0002565674,0.0003640815,0.0003068611,0.00003202221],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008148576,"about_ca_system_score_gemma":0.0001209733,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003395798,"about_ca_topic_score_gemma":0.000008056242,"domain_scores_codex":[0.9979886,0.000007722652,0.0004534927,0.0006848407,0.0003972366,0.0004680718],"domain_scores_gemma":[0.9979681,0.00004313969,0.0003841132,0.0010515,0.0001643145,0.0003887771],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001086119,0.0001128534,0.0008818108,0.0007785087,0.00008353718,0.00003260783,0.0002144944,0.000003337655,0.9953409,0.000003290005,0.0008560443,0.001584004],"study_design_scores_gemma":[0.001212973,0.00002010642,0.0006852795,0.000178136,0.0001127778,0.0000641763,0.0001036831,0.00001095867,0.9964793,0.00005179326,0.0006202418,0.0004605827],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991391,0.0006654369,0.00002252674,0.0005194195,0.00007942619,0.0001157469,0.000153733,0.0001115936,0.006941118],"genre_scores_gemma":[0.9981191,0.0003234406,0.0002020522,0.00008211173,0.0005366979,0.0000362616,0.00009180669,0.00007148058,0.0005370229],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006728127,"threshold_uncertainty_score":0.999814,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009592730516453226,"score_gpt":0.2346153448046583,"score_spread":0.2250226142882051,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}