{"id":"W2768991348","doi":"10.1021/acs.organomet.7b00728","title":"Synthesis, Structures, and Redox Properties of Tetracyano-Bridged Diferrocene Donor–Acceptor–Donor Systems","year":2017,"lang":"en","type":"article","venue":"Organometallics","topic":"Ferrocene Chemistry and Applications","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"Council of Scientific and Industrial Research, India; Department of Science and Technology, Ministry of Science and Technology, India; Indian National Science Academy","keywords":"Tetracyanoethylene; Chemistry; Ferrocene; Tetracyanoquinodimethane; HOMO/LUMO; Quadrupole splitting; Acceptor; Cycloaddition; Crystallography; Redox; Photochemistry; Mössbauer spectroscopy; Molecule; Electrochemistry; Inorganic chemistry; Physical chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001262558,0.0001943274,0.000274656,0.0001782626,0.000250022,0.0002678278,0.0004278928,0.0002880956,0.001120635],"category_scores_gemma":[0.0001841675,0.0001533292,0.00009393426,0.0001963118,0.000134444,0.0002114773,0.0001616828,0.0003543744,0.0002799082],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006137061,"about_ca_system_score_gemma":0.0001555542,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004640834,"about_ca_topic_score_gemma":0.001112364,"domain_scores_codex":[0.9998991,0.00001376146,0.00001111979,0.00002936019,0.00002621115,0.00002041684],"domain_scores_gemma":[0.9999295,0.000009533801,0.0000142259,0.00001050819,0.00001505214,0.00002116163],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005342323,0.00003482847,0.000113586,0.00006814805,0.000004634191,0.00005393947,0.00003898342,0.0002285738,0.9970406,0.0002980649,0.000066352,0.001998919],"study_design_scores_gemma":[0.00002996755,0.0002646298,0.0007739834,0.000004597794,0.00001413613,0.00009452979,0.00002421676,0.00138901,0.9939818,0.00006690028,0.003348336,0.000007935326],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9924086,0.0009046945,0.003590908,0.00009175012,0.00002432475,0.00006257018,0.0002666436,0.00006376419,0.002586646],"genre_scores_gemma":[0.9916909,0.0005434926,0.005515139,0.00003622273,0.000006010719,0.00005703442,0.0003975302,0.00001868481,0.001734967],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001120635,"threshold_uncertainty_score":0.004452765,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02412397950300341,"score_gpt":0.2319977615985197,"score_spread":0.2078737820955163,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}