{"id":"W2769392556","doi":"10.1021/acs.orglett.7b03118","title":"Asymmetric Fe<sup>II</sup>-Catalyzed Thia-Michael Addition Reaction to α,β-Unsaturated Oxazolidin-2-one Derivatives","year":2017,"lang":"en","type":"article","venue":"Organic Letters","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Institut Universitaire de France; Université Paris-Sud; Natural Sciences and Engineering Research Council of Canada; Centre National de la Recherche Scientifique; Fonds de recherche du Québec – Nature et technologies; Université Laval","keywords":"Chemistry; Enantioselective synthesis; Catalysis; Michael reaction; Chelation; Combinatorial chemistry; Addition reaction; Organic chemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003081722,0.0004406926,0.000448549,0.0003669411,0.0008929794,0.0002661128,0.0009572291,0.0003200309,0.0008512774],"category_scores_gemma":[0.001880502,0.0004703247,0.0001501909,0.0004546115,0.0001503762,0.0007226382,0.0002836589,0.0004974967,0.0004043542],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000562994,"about_ca_system_score_gemma":0.00007650097,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001763593,"about_ca_topic_score_gemma":0.00001506624,"domain_scores_codex":[0.9976064,0.0000640319,0.0004586272,0.0007788397,0.0005107173,0.0005813954],"domain_scores_gemma":[0.9972439,0.0002572603,0.0004773676,0.001668867,0.0001408246,0.000211799],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007661603,0.000122049,0.0002313037,0.00004316976,0.000112122,0.00001727841,0.0004382341,0.000001154342,0.9803606,0.00002763456,0.01348563,0.005084162],"study_design_scores_gemma":[0.000553629,0.00002776424,0.004180121,0.0001656511,0.00007070914,0.00001990628,0.0001678426,0.00004251557,0.990688,0.00007181396,0.003464901,0.0005471403],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9855554,0.00003180636,0.0008964743,0.01017735,0.0001113199,0.0002586824,0.00007454785,0.000818567,0.002075887],"genre_scores_gemma":[0.9949949,0.00003947329,0.00199307,0.001719972,0.0005179099,0.0000986795,0.0002288121,0.0001338028,0.0002734209],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01032736,"threshold_uncertainty_score":0.9997749,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01825211403862959,"score_gpt":0.2434840935319074,"score_spread":0.2252319794932779,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}