{"id":"W2770642977","doi":"10.1021/acs.macromol.7b02070","title":"Dual Location, Dual Acidic pH/Reduction-Responsive Degradable Block Copolymer: Synthesis and Investigation of Ketal Linkage Instability under ATRP Conditions","year":2017,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"Concordia University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Copolymer; Chemistry; Atom-transfer radical-polymerization; Ethylene glycol; Disulfide Linkage; Combinatorial chemistry; Polymer chemistry; Polymerization; Covalent bond; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001196939,0.0002285013,0.0002822806,0.00006910104,0.0006441194,0.000109381,0.000157831,0.0001614616,0.0003369963],"category_scores_gemma":[0.0003929046,0.0002382472,0.00007047784,0.00008601766,0.0009889607,0.0003797206,0.00009924205,0.000132819,0.000009641842],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004873318,"about_ca_system_score_gemma":0.0001374576,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002358913,"about_ca_topic_score_gemma":0.0000518059,"domain_scores_codex":[0.9986811,0.00007005811,0.0004023003,0.0003952389,0.0002282508,0.0002230677],"domain_scores_gemma":[0.9984086,0.0001726952,0.000482517,0.0006133692,0.0001995162,0.0001232612],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004979009,0.00007264384,0.004831853,0.0001445322,0.00008048512,0.000004847015,0.0003590753,0.00001703484,0.9917566,0.00119508,0.000041864,0.00144625],"study_design_scores_gemma":[0.0002743526,0.00001715964,0.02852109,0.0001246731,0.0001074652,0.00005409528,0.0008164934,0.00008971427,0.9688005,0.0008698722,0.00008717078,0.0002373507],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971325,0.0004362543,0.0003312047,0.0007146311,0.0001068773,0.0001020065,0.0002946858,0.00005858978,0.000823231],"genre_scores_gemma":[0.9989179,0.00007971146,0.0002639029,0.00002945855,0.0001304002,0.0000583902,0.0001320267,0.00003184882,0.0003562988],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02368924,"threshold_uncertainty_score":0.971544,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0158720131259751,"score_gpt":0.2507978048629614,"score_spread":0.2349257917369863,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}